ERC Publications

281) Stereoinvertive SN1 Through Neighboring Group Participation

Rahul Suresh, Noam Orbach and Ilan Marek

ERC Publications

Angew. Chem. Int. Ed. 2024, e202407602

275) Selective Terminal Functionalization of Linear Alkanes

Jeffrey Bruffaerts, Inbar Kesten, Keren Buhnik-Rosenblau, Anthony Cohen, Nurit Edri, Morgan Cormier, Yuanfei Zhang, Guo-Ming Ho, Itai Massad, Hila Halfon-Verner, Yechezkel Kashi, Ilan Marek

ERC Publications

Angew. Chem. Int. Ed. 2023, 62, e202306343

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273) Highly Diastereoselective Preparation of Tertiary Alkyl Isonitriles by Stereoinvertive Nucleophilic Substitution at a Nonclassical Carbocation

Xu Chen and Ilan Marek

ERC Publications

Org. Lett. 2023, 25, 2285–2288

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272) Stereospecific Nucleophilic Substitution at Quaternary Carbon Stereocenters

Xu Chen, Kaushalendra Patel, Ilan Marek

ERC Publications

Chem, 2023, 9, 266-279

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271) Stereoselective Construction of Tertiary Homoallyl Alcohols and Ethers by Nucleophilic Substitution at Quaternary Carbon Stereocenter

Xu Chen, Kaushalendra Patel, and Ilan Marek

ERC Publications

Angew. Chem. Int. Ed. 2023, 62, e202212425

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267) Regio- and Diastereoselective Carbometalation Reaction of Cyclopropenes

Yair Cohen, Ilan Marek

ERC Publications

Acc. Chem. Res. 2022, 55, 2848−2868

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266) Stereoselective Synthesis of Polysubstituted Spiropentanes

Yair Cohen, Dor Toledano, Ilan Marek

ERC Publications

J. Am. Chem. Soc. 2022, 144, 16732–16736

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265) Borylated Cyclopropanes as Spring-Loaded Entities: Access to Vicinal Tertiary and Quaternary Stereocenters in Acyclic Systems

Andre U. Augustin, Sergio Di Silvio, Ilan Marek

ERC Publications

J. Am. Chem. Soc. 2022, 144, 16298−16302

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264) Preparation of Distant Quaternary Carbon Stereocenters by Double Selective Ring-Opening of 1,1-Biscyclopropyl Methanol Derivatives

Yogesh Siddaraju, Juliette Sabbatani, Anthony Cohen and Ilan Marek

ERC Publications

Angew. Chem. Int. Ed. 2022, 61, e202203652

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263) Stereoinvertive Nucleophilic Substitution at Quaternary Carbon Stereocenters of Cyclopropyl Ketones and Ethers

Xu Chen and Ilan Marek

ERC Publications

Angew. Chem. Int. Ed. 2022, 61, e202203673

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262) Stereospecific Construction of Quaternary Carbon Stereocenters from Quaternary Carbon Stereocenters

Kaushalendra Patel, Veeranjaneyulu Lanke, and Ilan Marek

ERC Publications

J. Am. Chem. Soc. 2022, 144, 7066−7071

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261) Mechanistic Insights on the Selectivity of the Tandem Heck-Ring-Opening of Cyclopropyldiol Derivatives

Anthony Cohen, Alexander Kaushansky and Ilan Marek

ERC Publications

JACS Au 2022, 2, 3, 687–696

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260) Stereoselective Synthesis Through Remote Functionalization

Itai Massad, Rahul Suresh, Lucas Segura, Ilan Marek

ERC Publications

Nature Synthesis, 2022, 1, 37-48

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259) Stereodivergent Access to Trisubstituted Alkenylboronate Esters through Alkene Isomerization

Lucas Segura, Itai Massad, Masamichi Ogasawara, and Ilan Marek

ERC Publications

Org. Lett. 2021, 23, 9194−9198

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257) Alkene Isomerization Revitalizes the Coates-Claisen Rearrangement

Itai Massad and Ilan Marek

ERC Publications

Angew. Chem. Int. Ed. 2021, 60, 18509 –18513

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256) Stereoselective Tandem Iridium-Catalyzed Alkene Isomerization-Cope Rearrangement of ω-diene Epoxides: Efficient Access to Acyclic 1,6-Dicarbonyl Compounds

Rahul Suresh, Itai Massad and Ilan Marek

ERC Publications

Chem. Sci. 2021, 12, 9328-9332

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250) Stereospecific Access to Allylboronic Esters Within Acyclic Systems Bearing Distant Tetrasubstituted Stereocenters

David Pierrot and Ilan Marek

ERC Publications

Angew. Chem. Int. Ed. 2020, 59, 20434-20438

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249) Stereospecific Nucleophilic Substitution at Tertiary and Quaternary Stereocentres

Veeranjaneyulu Lanke and Ilan Marek

ERC Publications

Chem. Sci. 2020, 11, 9378-9385

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248) Stereoselective Preparation of Distant Stereocenters (1,5) within Acyclic Molecules

Anthony Cohen, Jean Chagneau, and Ilan Marek

ERC Publications

ACS Catal. 2020, 10, 7154−7161

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244) Construction of Acyclic Vicinal Tertiary and Quaternary Carbon Stereocenters via a Pd-Catalyzed Allylic Alkylation of Stereodefined Polysubstituted Ketene Aminals

Jianqiang Huang and Ilan Marek

ERC Publications

Eur. J. Org. Chem. 2020, 3133-3137

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243) Ru-Catalyzed Isomerization of w-Alkenylboronates towards Stereoselective Synthesis of Vinylboronates with Subsequent in-situ Functionalization

Guo-Ming Ho, Lucas Segura and Ilan Marek

ERC Publications

Chem. Sci. 2020, 11, 5944 - 5949

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241) Alkene Isomerization through Allylmetals as a Strategic Tool in Stereoselective Synthesis

Itai Massad and Ilan Marek

ERC Publications

ACS Catal. 2020, 10, 5793−5804

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237) Catalytic Enantioselective Cyclopropenation of Internal Alkynes: Access to Difluoromethylated Three-Membered Carbocycles

Zhi-Qi Zhang, Meng-Meng Zheng, Xiao-Song Xue, Ilan Marek, Fa-Guang Zhang, Jun-An Ma

ERC Publications

Angew. Chem. Int. Ed. 2019, 58, 18191-18196

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236) Diastereoselective Ring Opening of Fully-Substituted Cyclopropanes via Intramolecular Friedel–Crafts Alkylation

Veerujaneyulu Lanke, Fa-Guang Zhang, Alexander Kaushansky and Ilan Marek

ERC Publications

Chem. Sci. 2019, 10, 9548-9554

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235) Regio- and Stereoselective Synthesis of Fully Substituted Silyl Enol Ethers of Ketones and Aldehydes in Acyclic Systems.

Peter-Yong Wang, Guillaume Duret and Ilan Marek

ERC Publications

Angew. Chem. Int. Ed. 2019, 58, 14995-14999

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234) Regio- and Diastereoselective Copper-Catalyzed Carbometalation of Cyclopropenylsilanes

Yair Cohen and Ilan Marek

ERC Publications

Org. Lett. 2019, 21, 9162-9165

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238) Enantioselective Synthesis of Vicinal Tertiary and Quaternary Carbon Stereogenic Centers Within an Acyclic Chain

David Pierrot and Ilan Marek

ERC Publications

Angew. Chem. Int. Ed. 2020, 59, 36-49

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233) Highly E-selective, Stereoconvergent Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling of Alkenyl Ethers

Guo-Ming Ho, Heiko Sommer and Ilan Marek

ERC Publications

Org. Lett. 2019, 21, 2913-2917

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232) A Tandem Iridium-catalyzed ‘Chain-walking’/Cope Rearrangement Sequence

Heiko Sommer, Tal Weissbrod and Ilan Marek

ERC Publications

ACS Catal. 2019, 9, 2400-2406

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231) Diastereo- and Enantioselective Preparation of Cyclopropanol and Cyclopropylamine Derivatives

Marwan Simaan and Ilan Marek

ERC Publications

Beilstein J. Org. Chem. 2019, 15, 752-760

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281) Stereoinvertive SN1 Through Neighboring Group Participation

275) Selective Terminal Functionalization of Linear Alkanes

273) Highly Diastereoselective Preparation of Tertiary Alkyl Isonitriles by Stereoinvertive Nucleophilic Substitution at a Nonclassical Carbocation

272) Stereospecific Nucleophilic Substitution at Quaternary Carbon Stereocenters

271) Stereoselective Construction of Tertiary Homoallyl Alcohols and Ethers by Nucleophilic Substitution at Quaternary Carbon Stereocenter

267) Regio- and Diastereoselective Carbometalation Reaction of Cyclopropenes

266) Stereoselective Synthesis of Polysubstituted Spiropentanes

265) Borylated Cyclopropanes as Spring-Loaded Entities: Access to Vicinal Tertiary and Quaternary Stereocenters in Acyclic Systems

264) Preparation of Distant Quaternary Carbon Stereocenters by Double Selective Ring-Opening of 1,1-Biscyclopropyl Methanol Derivatives

263) Stereoinvertive Nucleophilic Substitution at Quaternary Carbon Stereocenters of Cyclopropyl Ketones and Ethers

262) Stereospecific Construction of Quaternary Carbon Stereocenters from Quaternary Carbon Stereocenters

261) Mechanistic Insights on the Selectivity of the Tandem Heck-Ring-Opening of Cyclopropyldiol Derivatives

260) Stereoselective Synthesis Through Remote Functionalization

259) Stereodivergent Access to Trisubstituted Alkenylboronate Esters through Alkene Isomerization

257) Alkene Isomerization Revitalizes the Coates-Claisen Rearrangement

256) Stereoselective Tandem Iridium-Catalyzed Alkene Isomerization-Cope Rearrangement of ω-diene Epoxides: Efficient Access to Acyclic 1,6-Dicarbonyl Compounds

250) Stereospecific Access to Allylboronic Esters Within Acyclic Systems Bearing Distant Tetrasubstituted Stereocenters

249) Stereospecific Nucleophilic Substitution at Tertiary and Quaternary Stereocentres

248) Stereoselective Preparation of Distant Stereocenters (1,5) within Acyclic Molecules

244) Construction of Acyclic Vicinal Tertiary and Quaternary Carbon Stereocenters via a Pd-Catalyzed Allylic Alkylation of Stereodefined Polysubstituted Ketene Aminals

243) Ru-Catalyzed Isomerization of w-Alkenylboronates towards Stereoselective Synthesis of Vinylboronates with Subsequent in-situ Functionalization

241) Alkene Isomerization through Allylmetals as a Strategic Tool in Stereoselective Synthesis

237) Catalytic Enantioselective Cyclopropenation of Internal Alkynes: Access to Difluoromethylated Three-Membered Carbocycles

236) Diastereoselective Ring Opening of Fully-Substituted Cyclopropanes via Intramolecular Friedel–Crafts Alkylation

235) Regio- and Stereoselective Synthesis of Fully Substituted Silyl Enol Ethers of Ketones and Aldehydes in Acyclic Systems.

234) Regio- and Diastereoselective Copper-Catalyzed Carbometalation of Cyclopropenylsilanes

238) Enantioselective Synthesis of Vicinal Tertiary and Quaternary Carbon Stereogenic Centers Within an Acyclic Chain

233) Highly E-selective, Stereoconvergent Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling of Alkenyl Ethers

232) A Tandem Iridium-catalyzed ‘Chain-walking’/Cope Rearrangement Sequence

231) Diastereo- and Enantioselective Preparation of Cyclopropanol and Cyclopropylamine Derivatives

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