Articles

2019

234) Enantioselective Synthesis of Vicinal Tertiary and Quaternary Carbon Stereogenic Centers Within an Acyclic Chain

David Pierrot and Ilan Marek
2019
Angew. Chem. Int. Ed. 2019, Accepted

233) Highly E-selective, Stereoconvergent Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling of Alkenyl Ethers

Guo-Ming Ho, Heiko Sommer and Ilan Marek
2019
Org. Lett 2019, 21, 2913-2917
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232) A Tandem Iridium-catalyzed ‘Chain-walking’/Cope Rearrangement Sequence

Heiko Sommer, Tal Weissbrod and Ilan Marek
2019
ACS Catalysis, 2019, 9, 2400-2406
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231) Diastereo- and Enantioselective Preparation of Cyclopropanol and Cyclopropylamine Derivatives

Marwan Simaan and Ilan Marek
2019
Beilstein Journal of Organic Chemistry, 2019, 15, 752-760
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230) Versatility in the Brook Rearrangement for Selective Ring-Opening of Three-Membered Rings Coralie Tugny, Fa-Guang Zhang and Ilan Marek

Coralie Tugny, Fa-Guang Zhang and Ilan Marek
2019
Chem. Eur. J. 2019, 25, 205-209
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2018

229) Convergent and Flexible Approach to Stereodefined Polyhydroxylated Fragments

Alexander Shtrenberg, Elvira Haimov, Polina Smirnov and Ilan Marek
2018
Tetrahedron (special issue for Prof. Leon Ghosez), 2018, 74, 6761-6768
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228) Diastereoselective Ring Opening of Alkenylcyclopropanes: Application to the Total Synthesis of C30 Botryococcene and epi-Botryococcene

Morgan Cormier, Aurelien de la Torre and Ilan Marek
2018
Angew. Chem. Int. Ed. 2018, 58, 13237-13241.
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227) Efficient and Stereodivergent Synthesis of Unsaturated Acyclic Fragments Bearing Contiguous Stereogenic Elements

Jeffrey Bruffaerts, David Pierrot and Ilan Marek
2018
Nature Chemistry, 2018, 10, 1164-1170
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226) Asymmetric Preparation of Polysubstituted Cyclopropanes Based on Direct Functionalization of Achiral Three-Membered Carbocycles

Longyang Dian and Ilan Marek
2018
Chemical Reviews (Focus) 2018, 118, 8415-8434
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225) Diastereo- and Enantioselective Copper Catalyzed Hydroallylation of Disubstituted Cyclopropenes

Heiko Sommer and Ilan Marek
2018
Chemical Science 2018, 9, 6503-6508
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224) Pd-Catalyzed Selective Remote Ring-Opening of Polysubstituted Cyclopropanols

Sukhbev Singh, Marwan Simaan and Ilan Marek
2018
Chem. Eur. J. 2018, 24, 8553-8557
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223) Metal-Catalyzed Remote Functionalization of -Ene Unsaturated Ethers as a New Entry to Functionalized Vinyl Species

Guo-Ming Ho, Lina Jiudkele, Jeffrey Bruffaerts and Ilan Marek
2018
Angew. Chem. Int. Ed. 2018, 57, 57, 8012-8016
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222) Asymmetric Rh-Catalyzed Arylation of Cyclopropenes Based on Directed Functionalization of Three-Membered Carbocycles (DFTMC)

Longyang Dian and Ilan Marek
2018
Angew. Chem. Int. Ed. 2018, 57, 3682-3686
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221) Walking Metals for Remote Functionalization

Heiko Sommer, Francisco Julia-Hernandez, Ruben Martin and Ilan Marek
2018
ACS Central Science 2018, 4, 153-165
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220) Rosarium Philosophorum on Organic Synthesis

Ilan Marek
2018
Isr. J. Chem. 2018, 58, 122-126
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219) Alkene-Zipper Catalyzed Selective and Remote Retro-Ene Reaction of Alkenyl Cyclopropylcarbinols

Jeffrey Bruffaerts, Alexandre Vasseur and Ilan Marek
2018
Adv. Synth. Catal. 2018, 360, 1389-1396
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218) Electrophilic Oxidation of Stereodefined Polysubstituted Silyl Ketene Aminals

Jian Qiang Huang, Zackaria Nairoukh and Ilan Marek
2018
Eur. J. Org. Chem. 2018, 614-618
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217) Electrophilic Fluorination of Stereodefined Polysubstituted Silyl Ketene Hemiaminals en route to Tertiary α-Fluorinated Carbonyl Derivatives

Jian Qiang Huang, Zackaria Nairoukh and Ilan Marek
2018
Org. Biomol. Chem. 2018, 16, 1079-1082
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216) Asymmetric Catalytic Preparation of Diastereo- and Enantiomerically Enriched Polysubstituted Cyclopropanol and Cyclopropylamine Derivatives

Marwan Simaan and Ilan Marek
2018
Angew. Chem. Int. Ed. 2018, 57, 1543-1546
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215) Zirconocene-Mediated Selective and Versatile C-C Bond Cleavage of Strained Carbocycles: Scope and Mechanism

Jeffrey Bruffaerts, Alexandre Vasseur, Sukhdev Singh, Ahmad Masarwa, Dorian Didier, Liron Oskar, Lionel Perrin, Odile Eisenstein and Ilan Marek
2018
J. Org. Chem. 2018, 83, 3947-3515
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2017

214) 2-Cl-MGV-1 Ameliorates Apoptosis in the Thalamus and Hippocampus and Cognitive Deficits after Cortical Infarct in Rats

Yicong Chen, Leo Veenman, Sukhdev Singh, Fubing Ouyang, Jiahui Liang, Weixian Huang, Ilan Marek, Jinsheng Zeng, and Moshe Gavish
2017
Stroke 2017, 48, 3366-3364
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213) Tandem Hydroalumination/Cu-Catalyzed Asymmetric Vinyl Metalation as a New Access to Enantioenriched Vinylcyclopropane Derivatives.

Daniel S. Müller, Veronika Werner, S. Akyol, Hans-Günther Schmalz and Ilan Marek
2017
Org. Lett. 2017, 19, 3970-3973
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212) Enantioselective Construction of Acyclic Quaternary Stereocenters: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Amide Enolates.

Pavel Starkov, Jared T. Moore, Douglas C. Duquette, Brian M. Stoltz and Ilan Marek
2017
J. Am. Chem. Soc. 2017, 139, 9615-9620
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211) Classical and Novel TSPO Ligands for the Mitochondrial TSPO can Modulate Nuclear Gene Expression: Implications for Mitochondrial Retrograde Signaling.

N. Yassin, L. Veeman, S. Singh, M. Azrad, J. Bode, A. Vainshtein, B. Caballero, I. Marek and M. Gavish.
2017
International Journal of Molecular Sciences 2017, 18, 786
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210) Brook Rearrangement as a Trigger for the Formation of Carbene: Formation of Stereodefined Fully-Substituted Cyclobutene Derivatives.

Fa-Guang Zhang and Ilan Marek
2017
J. Am. Chem. Soc. 2017, 139, 8364-8370
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209) Merging C-H and C-C Bonds Cleavage in Organic Synthesis

Zackaria Nairoukh, Morgane Cormier and Ilan Marek
2017
Nature Rev. Chem. 2017, 1, 0035
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208) Asymmetric Copper-Catalyzed Carbomagnesiation of Cyclopropenes.

Longyang Dian, Daniel S. Müller and Ilan Marek
2017
Angew. Chem. Int. Ed. 2017, 56, 6783-6787
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207) Palladium-Catalyzed Oxidative Cyclization of Aniline-Tethered Alkylidenecyclopropanes with O₂; A Facile Protocol to Selectively Synthesize 2- and 3-Vinylindoles.

Bo Cao, Marwan Simaan, Ilan Marek, Yin Wei and Min Shi
2017
Chemical Communications 2017 201, 53, 216-219
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206) A Unique Pd-Catalyzed Heck Arylation as a Remote Trigger for Cyclopropane Selective Ring-Opening

Sukhdev Singh, Jeffrey Bruffaerts, Alexandre Vasseur and Ilan Marek
2017
Nature Communications 2017, 8, 14200
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205) Enantioselective Allylic Alkylation of Stereodefined Polysubstituted Copper Enolates as an Entry to Acyclic Quaternary Carbon Stereocentre

Zackaria Nairoukh, Gunda GKS Narayana Kumar, Yury Minko and Ilan Marek
2017
Chemical Science 2017, 8, 627-630
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204) Diastereoselective Carbometalation of Cyclobutenes

Sudipto Raha Roy, Hendrik Eijsberg, Jeffrey Bruffaerts and Ilan Marek
2017
Chemical Science 2017, 8, 334-339
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2016

203) Zirconocene-Assisted Remote Cleavage of C-C and C-O Bonds: Application to Acyclic Stereodefined Metalated Hydrocarbons

Jeffrey Bruffaerts, David Pierrot and Ilan Marek
2016
Organic and Biomolecular Chemistry 2016, 14, 10325-10330
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202) Formation of Carbon Quaternary Stereogenic Center in Acyclic Systems via a Sequence of Carbometalation − Intramolecular Cyclization − Silicon Activation

Maya Preshel-Zlatsin, Fa-Guang Zhang, Guillaume Eppe and Ilan Marek
2016
Synthesis 2016, 48, 3279-3286
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201) Oxidation of bis-Sulfinyl Carbanion as the Pivot of Ionic/Radical Tandem Reactions

Guillaume Vincent, Saloua Chelli, Rocio Martinez Mallorquin, Adi Abramovitch, Sophie Beauvière, Catherine Gomez, Franck Brebion, Ilan Marek, Max Malacria, Jean Philippe Goddard and Louis Fensterbank
2016
Compte Rendu Academie des Sciences 2016, 19, 403-411
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200) Preparation and Reactivity of Acyclic Chiral Allylzinc Species via a Zn-Brook Rearrangement

Markus Leibelling, Khriesto A. Shurrush, Veronika Werner, Lionel Perrin and Ilan Marek
2016
Angew. Chem. Int. Ed. 2016, 55, 6057-6061
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199) Diastereodivergent Combined Carbometalation − Zinc Homologation – C-C Fragmentation Reaction as an Efficient Tool to Prepare Acyclic Allylic Quaternary Carbon Stereocenters

Sudipta Raha Roy, Dorian Didier, Amir Kleiner and Ilan Marek
2016
Chemical Science 2016, 7, 5989-5994
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198) Brook Rearrangement as a Trigger for Ring-Opening strained Carbocycles

Fa-Guang Zhang, Guillaume Eppe and Ilan Marek
2016
Angew. Chem. Int. Ed. 2016, 55, 714-718
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197) Stereoselective Formation of Trisubstituted Ketone Enolates

Elvira Haimov, Zackaria Nairoukh, Alexandre Shterenberg, Tiran Berkowitch, Timothy F. Jamison and Ilan Marek
2016
Angew. Chem. Int. Ed. 2016, 55, 5517-5520
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196) Remote Functionalization

Alexandre Vasseur, Jeffrey Bruffaerts and Ilan Marek
2016
Nature Chem. 2016, 8, 209-219
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195) Copper mediated carbometalation reactions

Daniel S. Müller and Ilan Marek,
2016
Chem. Soc. Rev. 2016, 45, 4552-4566
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194) Merging Allylic C-H Bond Activation and C-C Bond Cleavage en route to the Formation of Quaternary Carbon stereocenter in Acyclic Systems

Alexandre Vasseur and Ilan Marek
2016
Nature Protocols 2016, 12, 74-87
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2015

193) Asymmetric Copper-Catalyzed Carbozincation of Cyclopropenes en route to the Formation of Diastereo- and Enantiomerically Enriched Polysubstituted Cyclopropanes

Daniel S. Müller and Ilan Marek
2015
J. Am. Chem. Soc. 2015, 137, 15414-15417
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192) Carbozincation of alkynes and alkenes

Genia Skulte, Hannah Cavender and Ilan Marek
2015
Org. React. 2015, 87, 507-763
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191) The Scientific Bridge: Fifty Years of Germany-Israel Diplomatic Relations

Helmut Schwarz, Itamar Willner and Ilan Marek
2015
Angew. Chem. Int. Ed. 2015, 51, 12182-12183
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190) Quinazoline-Based Tricyclic Compounds that Regulate Programmed Cell Death, Induce Neuronal Differentiation, and are Curative in Animal Models for Excitoxicity and Hereditary Brain Disease

A. Vainshtein, L. Veenman, A. Shterenberg, S. Singh, A. Masarwa, B. Dutta, B. Island, E. Tsoglin, E. Levin, S. Leschiner, I. Maniv, L. Pe’er, I. Otradnov, S. Zubedat, S. Mizrachi, A. Weizman, A. Avital, Ilan Marek and M. Gavish
2015
Cell Death Discovery 2015, 1, 15027
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189) Stereodefined Acyclic Trisubstituted Silyl Enol Ethers Towards the Asymmetric Formation of Aldol Products Possessing Quaternary Carbon Stereocenters

Zackaria Nairoukh and Ilan Marek
2015
Angew. Chem. Int. Ed. 2015, 54, 14933-14937
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188) Gold(I)-Catalyzed Cycloisomerization of Vinylidenecyclopropane-enes via Carbene or non-Carbene Processes

De-Yao Li, Yin Wei, Ilan Marek, Xiang-Ying Tang and Min Shi
2015
Chemical Science 2015, 6, 5519-5525
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187) Forming Stereogenic Centers in Acyclic Systems from Alkynes

Roxane Vabre, Biana Island, Claudia J. Diehl, Peter R. Schreiner and Ilan Marek
2015
Angew. Chem. Int. Ed. 2015, 54, 9996-999
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186) Probing the Limits of NMR and VCD Spectroscopies in the Stereochemical Assignment of Chiral ²H₆-Neopentane

Ahmad Masarwa, Dennis Gerbig, Liron Oskar, Aharon Loewenstein, Hans Peter Reisenauer, Philipe Lesot, Peter R. Schreiner and Ilan Marek
2015
Angew. Chem. Int. Ed. 2015, 54, 13106-13109
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185) Formation of Several Carbon-Carbon Bonds in Acyclic Systems

Guillaume Eppe, Dorian Didier and Ilan Marek
2015
Chemical Reviews 2015, 105, 9175-9206
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184) Cyclopropene Derivatives as a New Entry to Enantioenriched Cyclopropanol and n-Butenal Possessing Quaternary Carbon Stereocenters

Marwan Simaan, Pierre-Olivier Delaye, Min Shi and Ilan Marek
2015
Angew. Chem. Int. Ed. 2015, 54, 12345-12348
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183) Remote Functionalization of Hydrocarbons with Reversibility Enhanced Stereocontrol

Alexandre Vasseur, Lionel Perrin, Odile Eisenstein and Ilan Marek
2015
Chemical Sciences 2015, 6, 2770-2776
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182) Gold and Silver-Catalyzed Intramolecular Cyclizations of Indolylcyclopropenes for the Divergent Synthesis of Azepinoindoles and Spiroindoline Piperidines

Peng-Long Zhu, Zhen Zhang, Xiang-Yiang Tang, Ilan Marek and Min Shi
2015
ChemCatChem 2015, 7, 595-600
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181) Selective Carbon-Carbon Bond Cleavage for the Stereoselective Synthesis of Acyclic Systems

Ilan Marek, Ahmad Masarwa, Pierre-Olivier Delaye and Markus Leibeling
2015
Angew. Chem. Int. Ed. 2015, 54, 414-429
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180) Electrophilic Amination: The Case of Nitrenoids

Pavel Starkov, Timothy F. Jamison and Ilan Marek
2015
Chem. Eur. J. 2015, 14, 5278-5300
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2014

179) Formation of Three New Bonds and Two Stereocenters in Acyclic Systems by Zinc-Mediated Asymmetric Alkynylation of Acylsilanes, Brook Rearrangement and Ene-Allene Carbocyclization Reactions

Polina Smirnov, Einat Katan, Jomon Mathew, Arseni Kostenko, Miriam Karni, Anne Nijs, Carsten Bolm, Yitzhak Apeloig and Ilan Marek
2014
J. Org. Chem. 2014, 79, 12122-12135
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178) Stereodefined Acyclic Trisubstituted Metal Enolates Towards the Asymmetric Formation of Quaternary Carbon Stereocentres

Yury Minko and Ilan Marek
2014
Chem. Comm. 2014, 50, 12597- 12611
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177) Isoxazole-Embedded Allylic Zinc Reagent for the Diastereoselective Preparation of Highly Functionalized Aldol-Type derivatives Bearing a Stereocontrolled Quaternary Center

Lydia Klier, Coura R. Diene, Manuel Schikinger, Albrecht Metzger, Andrea J. Wagner, Konstantin Karaghiosoff, Ilan Marek and Paul Knochel
2014
Chem.-Eur. J. 2014, 20, 20, 14096-14101
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176) Chemistry in Israel−at a Crossroads? (Editorial)

Ilan Marek
2014
Angew. Chem. Int. Ed. 2014, 53, 3754-3755
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175) All-Carbon Quaternary Stereogenic Centers in Acyclic System through the Creation of Several C-C bonds per Chemical Steps

Ilan Marek, Yury Minko, Morgane Pasco, Tom Mejuch, Noga Gilboa, Helena Chechik and Jaya P. Das
2014
J. Am. Chem. Soc. 2014, 136, 2682-2694
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174) Highly Diastereoselective Preparation of Aldol Products Using New Functionalized Allylic Aluminum Reagents

Zhi-Liang Shen, Zhihua Peng, Chun-Ming Yang, Julian Helberg, Peter Mayer, Ilan Marek and Paul Knochel
2014
Org. Lett. 2014, 16, 956-959
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173) Oxenoids in Organic Synthesis

Yury Minko and Ilan Marek
2014
Organic and Biomolecular Chemistry 2014, 12, 1535-1546
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172) Advances in Carbolithiation

Yury Minko and Ilan Marek
2014
In Lithium Compounds in organic Synthesis: From Fundamentals to Applications, First Edition. Edited by Renzo Luisi and Vito Capriati. Wiley-VCH 2014, 329-350
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171) Carbometalation Reactions

Dorian Didier and Ilan Marek
2014
In Copper-catalyzed Asymmetric Synthesis, First Edition. Edited by Alexandre Alexakis, Norbert Krause and S. Woodward. Wiley-VCH, 2014, 267-282.
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170) Merging Allylic C-H Activation and Selective C-C Bond Activation

Ahmad Masarwa, Dorian Didier, Tamar Zabrodsky, Marvin Schinkel, Lutz Ackermann and Ilan Marek
2014
Nature 2014 505, 199-203
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169) Modulable and Highly Diastereoselective Carbometalations of Cyclopropenes

Dorian Didier, Pierre-Olivier Delaye, Marwan Simaan, Biana Island, Guillaume Eppe, Hendrik Eijsberg, Amir Kleiner, Paul Knochel and Ilan Marek
2014
Chem. Eur. J. 2014, 20, 1038-1048
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168) Carbometalation Reactions

Ilan Marek and Yury Minko in Metal-Catalyzed Cross-Coupling Reactions and More- First edition
2014
Eds de Meijere, A., Oestreich, M., Brase, S. Wiley-VCH,2014, 769-
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2013

167) A One-Pot Zinc-promoted Asymmetric Alkynylation/Brook-Type Rearrangement/Ene-Allene Cyclization: Highly Selective Formation of Three New bonds and two Stereocenters in Acyclic Systems

Polina Smirnov, Jomon Mathew, Anne Nijs, Einat Katan, Miriam Karni, Carsten Bolm, Yitzhak Apeloig and Ilan Marek
2013
Angew. Chem. Int. Ed. 2013, 52, 13717-13721
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166) Carboxylate-Assistance for Catalyzed Hydroarylations of Methylenecyclopropanes

Marvin Schinkel, Jan Wallbaum, Sergei I. Kozhushkov, Ilan Marek and Lutz Ackermann
2013
Org. Lett. 2013, 15, 4482-4484
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165) Stereodefined Trisubstituted Enolates as a Unique Entry to All-Carbon Quaternary Stereogenic Centres in Acyclic Systems

Yury Minko, Morgane Pasco, Lukas Lecher and Ilan Marek
2013
Nature Protocols 2013, 4, 749-754
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164) Axial Preferences in Allylation Reactions via the Zimmerman – Traxler Transition State

Tom Mejuch, Noga Gilboa, Eric Gayon, Hao Wang, K. H. Houk and Ilan Marek
2013
Acc. Chem. Res. 2013, 46, 1659-1669
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163) Regio- and Stereoselective Carbometallation Reactions of N-Alkynyl-Amides and Sulfonamides

Yury Minko, Morgane Pasco Helena Chechik and Ilan Marek
2013
Beilstein J. Org. Chem. 2013, 9, 526-532.
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162) The Renaissance of Zinc Carbenoid in Stereoselective Synthesis in Acyclic systems

Morgane Pasco, Noga Gilboa, Tom Mejuch and Ilan Marek
2013
Organometallics 2013, 32, 942-950
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161) Carbon-Carbon Bond Activation en Route to the Formation of all-Carbon Quaternary Stereogenic Centers in Acyclic Systems

Pierre-Olivier Delaye, Dorian Didier and Ilan Marek
2013
Angew. Chem. Int. Ed. 2013, 52, 5333-5337
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160) Carboxylate-assisted Ruthenium(II)-Catalyzed C-H Arylation of 5-Aryl Tetrazoles: Step-Economical Access to Valsartan

Emelyne Diers, N. Y. Phani Kumar, Tom Mejuch, Ilan Marek and Lutz Ackermann
2013
Tetrahedron 2013, 69, 4445-4453
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159) New Advances in Bis(sulfoxides) Chemistry

Sophie Beauvière, Franck Brebion, Saloua Chelli, Bénédicte Delouvrié, Catherine Gomez, Ophélie Kwasnieski, Rocio Martinez Mallorquin, Francisco Najera, Guillaume Vincent, Maxime R. Vitale, Etienne Derat, Ilan Marek, Max Malacria, Jean-Philippe Goddard and Louis Fensterbank
2013
Phosphorus Silicon & Related 2013, 188, 367-376
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158) Carboxylate-Assisted Ruthenium(II)-Catalyzed Hydroarylations of Unactivated Alkenes via C–H Cleavage

Marvin Schinkel, Ilan Marek and Lutz Ackermann
2013
Angew. Chem. Int. Ed. 2013, 52, 3977-3980
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2012

157) Alkenyl Zinc Reagents in Cross-Coupling Reactions In Cross-Coupling and Heck-Type Reactions 1 − C-C Cross Coupling Using Organometallic Partners

Tom Mejuch and Ilan Marek
2012
Science of Synthesis 2012, 765-794

156) Forming All-Carbon Quaternary Stereogenic Centres in Acyclic Systems from Alkynes

Yury Minko, Morgane Pasco, Luckas Lercher, Mark Botoshansky and Ilan Marek
2012
Nature 2012, 490, 522
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155) Convergent Diastereoselective Preparation of Adjacent Quaternary Stereocenters in an Acyclic System

Tom Mejuch, Bishnu Dutta, Mark Botoshansky and Ilan Marek
2012
Organic and Biomolecular Chemistry 2012, 10, 5803-5806 (Special issue for 10th Birthday)
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2011

154) Efficient Brønsted Acid Catalyzed Hydrations and Hydroaminations of (Dicyclopropylmethylene) cyclopropane

Lutz Ackermann, Sergei I. Kozhushkov, Dmitry S. Yufit and Ilan Marek
2011
Synlett 2011, 1515-1518
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153) Combined Carbometalation–Zinc Homologation–Allylation Reactions as a New Approach for Alkoxyallylation of Aldehyde

Tom Mejuch, Mark Botoshansky and Ilan Marek
2011
Org. Lett. 2011, 13, 3604-3607
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152) Conjugate Additions to Alkylidene Bis-sulfoxides

Frank Brebion, Guillaume Vincent, Saloua Chelli, Ophelie Kwasnieski, Francisco Najera, Benedicte Delouvrie, Ilan Marek, Etienne Derat, Jean-Philippe Goddard, Max Malacria and Louis Fensterbank
2011
Chem. Asian J. 2011, 6, 1825-1833
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151) Axial Preferences in Allylation via the Zimmerman-Traxler Transition State

Noga Gilboa, Hoa Wang, Ken N. Houk and Ilan Marek
2011
Chem. Eur. J. 2011, 17, 8000-800
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150) Carbometalation of Carbon-Carbon Double Bonds in Stereoselective Carbometalation of Carbon-Carbon Double Bonds

Ilan Marek and Ahmad Basheer
2011
Stereoselective Synthesis 1 in Science of Synthesis Ed: J. G. de Vries, 2011, 325-408
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149) Enantioselective Synthesis of all-Carbon Quaternary Stereogenic Centers in Acyclic Systems

Jaya P. Das and Ilan Marek
2011
Chem. Commun. (Feature article) 2011, 47, 4593-4623

147) Regioselective Carbon-Carbon Bond Cleavage in the Oxidation of Cyclopropenylcarbinols

Ahmad Basheer, Massaki Mishima and Ilan Marek
2011
Org. Lett. 2011, 13, 4076-4079

2010

148) Recent Advances in Carbocupration of α-Heterosubstituted Alkynes

Ahmad Basheer and Ilan Marek
2010
Beilstein J. Org. Chem. 2010, 6, No. 77. doi:10.3762/bjoc.6.77

146) Selectivity in Metal-Catalyzed Carbon-Carbon Bond Cleavage of Alkylidenecyclopropanes

Ahmad Masarwa and Ilan Marek
2010
Chem. Eur. J. 2010, 16, 9712-9721

145) Diastereo- and Enantioselective Intramolecular Carbometalation Reaction

Rozalia Unger, Theodore Cohen and Ilan Marek
2010
Tetrahedron 2010, 66, 4874-4881

144) Highly Diastereoselective Preparation of Homoallylic Alcohols Containing Two Contiguous Quaternary Stereocenters in Acyclic Systems from Simple Terminal Alkynes

Bishnu Dutta, Noga Gilboa and Ilan Marek
2010
J. Am. Chem. Soc. 2010, 132, 5588-5589

143) Hydroformylation Reaction of Alkylidenecyclopropane Derivatives: A new Pathway for the Formation of Acyclic Aldehydes Containing Quaternary Stereogenic Carbons

Samah Simaan and Ilan Marek
2010
J. Am. Chem. Soc. 2010, 132, 4066-4067

142) The Superiority of Properly Prepared Lithium 1-N,N-Dimethylaminonaphthalenide (LDMAN) over Other Aromatic Radical-anions for the Generation of Organolithiums by Reductive Lithiation

Roman Ivanov, Ilan Marek and Theodore Cohen
2010
Tetrahedron Lett. 2010, 51, 174-176

141) Regiodivergent Carbometalation Reactions of Ynol Ether Derivatives

Anat Levin, Ahmad Basheer and Ilan Marek
2010
Synlett 2010, 329.

140) Metal-Catalyzed Ring-Opening of Alkylidenecyclopropanes as a New Approach to the Preparation of Enantiomerically Pure all-Carbon Quaternary Stereocenters

Samah Simaan, Alex F. G. Golberg, Stephane Rosset and Ilan Marek
2010
Chem. Eur. J. 2010, 16, 774.

2009

139) Enantioselective Preparation of Enantiomerically Pure Cyclobutene Derivatives

Ahmad Masarwa, Alois Fürstner and Ilan Marek
2009
Chem. Commun. 2009, 5760-5762

138) Preface for a special issue of Chemistry, A European Journal dedicated to Yitzhak Apeloig

Miri Karni, Ilan Marek and Sason Shaik
2009
Chem. Commun. 2009, 5760-5762

137) Cyclopropenylcarbinol Derivatives: New Versatile Intermediates in Organic Synthesis. Application to the Formation of Enantiomerically Pure Alkylidenecyclopropane Derivatives.

Samah Simaan, Ahmad Masarwa, Elinor Zohar, Amnon Stanger, Philippe Bertus and Ilan Marek
2009
Chem. Eur. J. 2009, 15, 8449-8464

136) The Basics of Zinc Activation (Perspectives)

Ilan Marek
2009
Science 2009, 326, 673-674

Tandem Zn-Brook Rearrangement/Ene-Allene Carbocyclization

Rozalia Unger, Theodore Cohen and Ilan Marek
2009
Eur. J. Org. Chem. 2009, 1749-1756

135) Tandem Zn-Brook Rearrangement/Ene-Allene Carbocyclization

Rozalia Unger, Theodore Cohen and Ilan Marek
2009
Eur. J. Org. Chem. 2009, 1749-1756

134) Enantioselective Construction of all-Carbon Quaternary Stereogenic Carbons in Aldol Reactions

Jaya P. Das, Helena Chechik and Ilan Marek
2009
Nature Chemistry, 2009, 1, 128-132

133) Diastereo- and Enantioselective Zinc Ene-Allene Carbocyclization

Rozalia Unger, Fritz Weisser, Nicka Chinkov, Amnon Stanger, Theodore Cohen and Ilan Marek
2009
Org. Lett. 2009, 11, 1853-1856

132) Copper-Catalyzed Hydride Transfer Towards the Formation of Alkylidenecyclopropane Derivatives

Samah Simaan and Ilan Marek
2009
Chem. Commun. 2009, 292-294

131) Stereoselective Synthesis of Metalated Cyclobutane Derivatives

Einav Tsoglin, Helena Chechik, Guy Karseboom, Nicka Chinkov, Amnon Stanger and Ilan Marek
2009
Advanced Synthesis and Catalysis 2009, 351, 1005-1008

2008

130) Zinc Homologation-Elimination Reaction of α-Sulfinyl Carbanions as a New Route to Olefins

Adi Abramovitch and Ilan Marek*
2008
Eur. J. Org. Chem. (2008) 4924-4931

129) Zinc Homologation-Elimination Reaction of α-Sulfinyl Carbanions as a New Route to Olefins

Adi Abramovitch and Ilan Marek
2008
Eur. J. Org. Chem. 2008, 4924-4931

128) Convergent Preparation of Enantiomerically Pure Polyalkylated Cyclopropane Derivatives

Adi Abramovitch, Louis Fensterbank, Max Malacria and Ilan Marek
2008
Angew. Chem. Int. Ed. 2008, 47, 6865-6868

127) A Shift in Retrosynthetic Paradigm (Concept article)

Ilan Marek
2008
Chem. Eur. J. 2008, 14, 7460-7468

126) Cyclopropenyllithiums as a New Source of 1,1-Bismetalated Cyclopropyl Derivatives

Anat Levin and Ilan Marek
2008
Chem. Commun. 2008, 4300

125) Synthesis of Sulfoximidoyl-Substituted Triazoles by Huisgen 1,3-Dipolar Cycloaddition

Bernhard Fuger, Genia Sklute, Ilan Marek, Gae Young Bolm and Carsten Bolm
2008
Synlett 2008, 116-118

2007

124) Intramolecular Carbozincation of Unactivated Alkenes Occurs Through a Zinc Radical Transfer Mechanism

Theodore Cohen, Heather Gibney, Roman Ivanov, Edmund A.-H. Yeh, Ilan Marek and Dennis P. Curran
2007
J. Am. Chem. Soc. 2007, 129, 15405-15409

123) Diastereodivergent Synthesis of Enantiomerically Pure Homoallylic Amine Derivatives Containing Quaternary Carbon Stereocenters

Goren Kolodney, Genia Sklute, Sylvie Perrone, Paul Knochel and Ilan Marek
2007
Angew. Chem. Int. Ed. 2007, 46, 9291-9294

122) An Efficient, Facile and General Stereoselective Preparation of Heterosubstituted Alkylidenecyclopropanes

Ahmad Masarwa, Amnon Stanger and Ilan Marek
2007
Angew. Chem. Int. Ed. 2007, 46, 8039-8042

121) Enantiomerically Enriched Cyclopropene Derivatives: Versatile Building Blocks in Asymmetric Synthesis

Ilan Marek, Samah Simaan and Ahmad Masarwa
2007
Angew. Chem. Int. Ed. 2007, 46, 7364-7376; (Corrigenda Angew. Chem. Int. Ed. 2008, 47, 1982)

120) Creation of Chiral Quaternary Stereocenters in the Carbonyl Allylation Reactions

Ilan Marek and Genia Sklute
2007
Chem. Commun. (Feature article), 2007, 43, 1683-1691

119) Stereodivergent Carbometalation Reactions of Cyclopropenylcarbinols Derivatives

Samah Simaan and Ilan Marek
2007
Org. Lett. 2007, 9, 2569-2571

118) Regio- and Stereoselective Copper-Catalyzed Carbozincation of Alkynylsulfoximines

Genia Sklute, Carsten Bolm and Ilan Marek
2007
Org. Lett. 2007, 9, 1259-1261

2006

117) A Zirconium Promenade; A Efficient Tool in organic Synthesis

Ilan Marek, Nicka Chinkov and Anat Levin
2006
Synlett (account), 2006, 501-514

116) Multicomponent Approach for the Creation of Chiral Quaternary Centers in the Carbonyl Allylation Reactions

Genia Sklute and Ilan Marek
2006
J. Am. Chem. Soc. 2006, 128, 4642-4649

115) Chiral Cyclopropenylcarbinols as a New Source of Chiral Alkylidenecyclopropane Derivatives

Samah Simaan, Ahmad Masarwa, Philippe Bertus and Ilan Marek
2006
Angew. Chem. Int. Ed. 2006, 45, 3963-3965

114) Unsaturated Fatty Alcohol Derivatives as a New Source of Substituted Allylzirconocenes

Nicka Chinkov, Anat Levin and Ilan Marek
2006
Angew. Chem. Int. Ed. 2006, 45, 465-468

2005

113) New Tandem Zn-Promoted Brook Rearrangement/Ene-Allene carbocyclization Reactions

Rozalia Unger, Theodore Cohen and Ilan Marek
2005
Org. Lett. 2005, 7, 5313-5316

112) Special issue of Tetrahedron Symposium-in-Print on Multicomponent Reactions

Ilan Marek
2005
Tetrahedron, 2005, 61, 11309-11519. Guest Editors

111) Stereoselective Functionalization of Cyclopropane Derivatives Using Bromine/Magnesium and Sulfoxide/Magnesium Exchange Reactions

Felix Kopp, Genia Sklute, Kurt Polborn, Ilan Marek and Paul Knochel
2005
Org. Lett. 2005, 7, 3789-3791

110) Preparation and Synthetic Transformation of Alkenyl Carbamate into Vinyl Zirconocene Derivatives

Helena Chechik-Lankin and Ilan Marek
2005
Synthesis 2005, 3311-3318

109) Functionalized Organozirconium and Titanium in Organic Synthesis In Functionalized Organometallic Derivatives

Ilan Marek and Helena Chechik-Lankin
2005
Ed. P. Knochel, Wiley-VCH, Weinheim, 2005, 503-540

108) Regiocontrolled Carbometallation Reactions of Ynamides

Helena Chechik-Lankin, Shulamit Livshin and Ilan Marek
2005
Synlett 2005, 2098-2100

107) Synthesis of Chiral Methylenecyclopropanes Derivatives

Elinor Zohar, Amnon Stanger and Ilan Marek
2005
Synlett 2005, 2239-2241

2004

106) Ambiphilic Zinc Carbenoid as a New Tool for Multicomponent Condensation Reactions

Ilan Marek
2004
Isr. Chem. Soc. 2004, 16, 22-32

105) Stereoselective Synthesis and Reactivity of Dienyl Zirconocene

Nicka Chinkov, Swapan Majumbar and Ilan Marek
2004
Practical Synthetic Procedures Synthesis, 2004, 2411-2417

104) New Regio-, Stereo-, Diastereo-, and Enantioselective One-Pot Reactions Mediated by Organometallic Derivatives

Nicka Chinkov, Genia Sklute, Helena Chechik, Adi Abramovitch, Deborah Amsallem, Jos, P. Varghese, Swapan Majumbar and Ilan Marek
2004
Pure and Applied Chem. 2004, 76, 517-535

103) Functionalized Organozirconium and Titanium in Organic Synthesis In Functionalized Organometallic Derivatives

Nicka Chinkov and Ilan Marek
2004
Springer Verlag, 2004, 133-166

102) The Preparation of Organolithium Compounds and Derivatives in The Chemistry of Organolithium Compounds

Frederic Leroux, Manfred Schlosser, Elinor Zohar and Ilan Marek
2004
Eds Rappoport, Z.; Marek, I., John Wiley & Sons, Chichester, 2004, 435-493

101) Carbometallation Reaction in Transition Metals for Fine Chemicals and Organic Synthesis-second edition

Daniella Tene and Ilan Marek
2004
Eds C. Bolm, M. Beller, Wiley-VCH, 2004, 563-573

100) Carbometalation Reaction in Metal-Catalyzed Cross-Coupling Reactions- second edition

Nicka Chinkov, Daniella Tene and Ilan Marek
2004
Eds F. Diederich, A. de Meijere Wiley-VCH, 2004, 395-478

99) Stereoselective Preparation of Deuteriated Dienes by Ring Fragmentation of Metallated Cyclopropylcarbinols

Elinor Zohar, Mirit Ram and Ilan Marek
2004
Synlett 2004, 1288-1290

98) Convenient Access to 2-(Trialkylstannyl)cyclopropylamines and Their Application in Palladium-Catalyzed Cross-Coupling Reactions

Stefan Wiedemann, Karsten Rauch, Andrei Savchenko, Ilan Marek and Armin de Meijere
2004
Eur. J. Org. Chem. 2004, 631-635

97) Diastereoselective Reduction of Cyclopropenylcarbinol: new Access to Anti-Cyclopropylcarbinol Derivatives

Elinor Zohar and Ilan Marek
2004
Org. Lett. 2004, 6, 341-343

96) α-Sulfinyl Carbanions as a New Source of Olefins

Adi Abramovitch, Jos P. Varghese and Ilan Marek
2004
Org. Lett. 2004, 6, 621-623

95) From Vinyl Sulfides, Sulfoxides and Sulfones to Vinyl Zirconocene Derivatives

Shahera Farhat, Irena Zouev and Ilan Marek
2004
Tetrahedron 2004, 60, 1329-1337

2003

94) Regio- and Stereoselective Synthesis of Novel E-Alkenyl Carbamate via Carbocupration Reaction

Helena Chechik and Ilan Marek
2003
Org. Lett. 2003, 5, 5087-5089

93) Stereoselective Preparation of Dienyl Zirconocene Complexes via a Tandem Allylic C-H bond Activation-Elimination Sequence

Nicka Chinkov, Swapan Majumdar and Ilan Marek
2003
J. Am. Chem. Soc. 2003, 125, 13258-13264

92) Four-Component Reactions for a New Diastereo- and Enantioselective Synthesis of Chiral Quaternary Centers.

Genia Sklute, Deborah Amsallem, Amal Shibli, Jos P. Varghese and Ilan Marek
2003
J. Am. Chem. Soc. 2003, 125, 11776-11777

91) Synthesis and Reactivity of Geminated Organobismetallic Derivatives

Ilan Marek
2003
Actualite Chimique, special issue on the Present and future in Chemistry, 2003, 17-24

90) Stereoselective Preparation of Functionalized Unsaturated Lactones and Esters via Functionalized Magnesium Compounds

Viet Anh Vu, Ilan Marek and Paul Knochel
2003
Synthesis, 2003, 1797-1802

89) Reaction of Allylzirconocene Compounds with Isolated or In Situ Generated η⁵ Pentadienyl Fe(CO)₃ /Fe(CO)₂ PPh₃(+1) Cations.

Leila Motiei, Ilan Marek, Hugo Gottlieb, Vered Marks and Jean-Paul (Moshe) Lellouche
2003
Tetrahedron Lett. 2003, 44, 5909-5912

2002

88) Sp3 Organozinc Carbenoid Homologation in Organic Synthesis

Ilan Marek
2002
Tetrahedron Report, 2002, 58, 9463-9475

87) New Approach to the Stereoselective Synthesis of Metallated Dienes via an Isomerization-Elimination Sequence

Nicka Chinkov, Swapan Majumdar and Ilan Marek
2002
J. Am. Chem. Soc. 2002, 124, 10282-10283

87) New Approach to the Stereoselective Synthesis of Metallated Dienes via an Isomerization-Elimination Sequence

Nicka Chinkov, Swapan Majumdar and Ilan Marek
2002
J. Am. Chem. Soc. 2002, 124, 10282-10283

86) New Preparation of Stereodefined α,β-Unsaturated Ketones by Carbomagnesiation of allenyl ketone

Nicka Chinkov, Natalia Morlender-Vais and Ilan Marek
2002
Tetrahedron Lett. 2002, 43, 6009-6010

85) New Methods for the Preparation of Sp2 Organometallic derivatives

Nicka Chinkov, Helena Chechik, Swapan Majumbar, Annie Liard and Ilan Marek
2002
Synthesis, 2002, 2473-2483

84) Carbocupration-Zinc Carbenoids Homologation and β-Elimination Reactions for a New Synthesis of Allenes. Applications to a New Synthesis of Chiral Allenes via Deracemization of Sp3 Organometallic Derivatives

Jos P. Varghese, Irena Zouev, Lionel Aufauvre, Paul Knochel and Ilan Marek
2002
Eur. J. Org. Chem. 2002, 4151-4158

83) Diastereoselective Reduction of Alkenylboronic Esters as a New Method for Controlling the Stereochemistry of up to Three Adjacent Centers and Acyclic Molecules

Eike Hupe, Ilan Marek and Paul Knochel
2002
Org. Lett. 2002, 4, 2861-2863

82) Functionalized Aminocyclopropanes from Functionalized Organozinc Compounds and N,N Dialkylcarboxamides

Stefan Wiedemann, Ilan Marek and Armin de Meijere
2002
Synlett 2002, 879-882

81) Catalytic Asymmetric and Stereoselective Synthesis of Vinyl Cyclopropanes

Swapan Majumdar, Armin de Meijere and Ilan Marek
2002
Synlett 2002, 423-426

80) From Vinyl Sulfides, Sulfoxides and Sulfones to Transition Metal Complexes k

Shahera Farhat and Ilan Mare
2002
Angew. Chem. Int. Ed. 2002, 41, 1410-1413

79) Preparation of New Functionalized Cyclopropylmagnesium Reagents

Viet Anh Vu, Ilan Marek, Kurt Polborn and Paul Knochel
2002
Angew. Chem. Int. Ed. 2002, 41, 351-352

2001

78) Preface for a special issue of the Journal of Organometallic Chemistry dedicated to Prof. Jean-F. Normant

Ilan Marek
2001
J. Organomet. Chem. 2001, 624, 1-3

77) Oxidative Addition-β-Elimination: A New Method for the Preparation of Organometallic Compounds

Annie Liard, Helena Chechik, Shahera Farhat, Natalia Morlender-Vais, Claudia Averbuj and Ilan Marek
2001
J. Organomet. Chem. 2001, 624, 26-33

76) Diastereoselective Carbozincation of Propargylic Amines

Hadi Rezaei, Ilan Marek and Jean F. Normant
2001
Tetrahedron 2001, 57, 2477-2483

75) Improved Preparation of Secondary Zinc Iodides by 1,2-Migration of sp3 Carbenoids

Amal Shibli, Jos P. Varghese, Paul Knochel and Ilan Marek
2001
Synlett 2001, 818-820

2000

74) Synthesis and Reactivity of sp2 Geminated Organobismetallics

Ilan Marek
2000
Chem. Rev. 2000, 100, 2887-2900

73) Carbometalation of Unactivated Alkynes via Low Valent Titanium Derivatives

Natalia Vais-Morlender, Nicka Solodovnikova and Ilan Marek
2000
Chem. Commun. 2000, 1849-1850

72) New Allene Synthesis via Carbocupration- Zinc Carbenoid Homologation and β-Elimination

Jos Varghese, Paul Knochel and Ilan Marek
2000
Org. Lett. 2000, 2, 2849-2852

71) Stereoselective Preparation of E-Vinyl Zirconium Derivatives from E or Z-Enol Ether

Annie Liard and Ilan Marek
2000
J. Org. Chem. 2000, 65, 7518-7220

70) First Synthesis and Reactivity of Functionalized Alkynyl Titanium Derivatives.

Natalia Vais-Morlender, Julia Kaftanov and Ilan Marek
2000
Synthesis, 2000, 917-920

69) Novel Stereoselective and Enantioselective Synthesis of Heterocyclic Compounds by Anionic Method

Edwige Lorthiois, Jean Normant and Ilan Marek
2000
Actual. Chim. 2000, 3, 60-61

68) Synthesis and Reactivity of Polymetallated Olefins and Functionalized Metallo-Alkynes

Julia Kaftanov, Natalia Vais-Morlender, Claudia Averbuj, Annie Liard and Ilan Marek
2000
Polyhedron 2000, 19, 563-566

67) New One-Pot Synthesis of ω-Iodoalkyne

Arindam Chakraborty and Ilan Marek
2000
Synthetic Comm. 2000, 30, 1895-1901

66) Fluoroform: An Efficient Precursor for the Trifluoromethylation of Aldehydes

Benoit Folleas, Ilan Marek and Jean F. Normant
2000
Tetrahedron 2000, 56, 275-283

1999

65) Enantioselective Carbometalation of Unactivated Olefins

Ilan Marek
1999
J. Chem. Soc. Perkin Trans. 1, 1999, 535-544

64) Iodine Transfer Cyclization Mediated by DIBAL-H/THF

Arindam Chakraborty and Ilan Marek
1999
Chem. Commun. 1999, 2375-2376

63) A New Approach Towards the Synthesis of sp3 1,1-Diiodoalkanes

Lionel Aufauvre, Paul Knochel and Ilan Marek
1999
Chem. Commun. 1999, 2207-2208

62) First Synthesis of Metallated Titanacyclopropenes

Claudia Averbuj, Julia Kaftanov and Ilan Marek
1999
Synlett 1999, 11, 1939-1941

61) Preparation and Reaction of Functionalized Magnesium Carbenoids

Salvatore Avolio, Christophe Malan, Ilan Marek and Paul Knochel
1999
Synlett 1999, 11, 1820-1822

60) The Allyl Zincation of Vinyl Metals. A Computational Study

Ilan Marek, Peter R. Schreiner and Jean F. Normant
1999
Org. Lett. 1, 1999, 929-931

59) Enantioselective Carbometalation of Cinnamyl Derivatives: New Access to Chiral Disubstituted Cyclopropanes. Configurational Stability of Benzylic Organozinc Halides

Stephanie Norsikian, Ilan Marek, Sophie Klein, Jean-Francois Poisson and Jean F. Normant
1999
Chem. Eur. J. 1999, 5, 2055

58) Diastereoselective contra-Michael addition of (-)-sparteine/organolithium complexes to secondary chiral cinnamyl amides

Nathalie Bremand, Ilan Marek and Jean F. Normant
1999
Tetrahedron Lett. 1999, 40, 3383-3386

57) Regioselective Addition of n-Butyllithium on Secondary Cinnamyl Amides Michael versus Contra-Michael Process

Nathalie Bremand, Ilan Marek and Jean F. Normant
1999
Tetrahedron Lett. 1999, 40, 3379-3382

56) First Transfer of Chirality in the Fritsch- Buttenberg-Wiechell Rearrangement, via Zinc Carbenoids: A Migration with Retention of Configuration

Isabelle Creton, Hadi Rezaei, Ilan Marek and Jean F Normant
1999
Tetrahedron Lett. 1999, 40, 1899-1902

1998

55) Preparation and Reaction of 1,n-bimetallic Reagents in Practical Approach in Organozinc Chemistry

Ilan Marek and Jean-F Normant
1998
Ed. Knochel, P. Oxford University Press, 1998, 119-137

54) Carbometallation Reactions in Metal-Catalyzed Cross-Coupling Reactions

Ilan Marek and Jean-F Normant
1998
Eds Stang, P.J., Diederich, F. Wiley-VCH, 1998, 271-337

53) Carbometalation Reactions in Transition Metals for Fine Chemicals and Organic Synthesis,

Ilan Marek and Jean-F Normant
1998
Eds. Bolm, C., Beller, C. Wiley-VCH, 1998, 514-522

52) Diastereoselective Carbometalation of Chiral Vinyl Metals

Denis Brasseur, Ilan Marek and Jean F. Normant
1998
C. R. Acad. Sci. Paris, t.1, Serie II c 1998, 621-625

51) First Diastereoselective Carbometalation of Chiral Vinyl Metals

Denis Brasseur, Hadi Rezaei, Alain Fuxa, Alex Alexakis, Pierre Mangeney, Ilan Marek and Jean F. Normant
1998
Tetrahedron Lett. 1998, 39, 4821-4824

50) Fluoroform: An Efficient Precursor for the Trifluoromethylation of Carbonyl Compounds

Benoit Folleas, Ilan Marek, Jean-F. Normant and Laurent Saint Jalmes
1998
Tetrahedron Lett. 1998, 39, 2973-2976

49) Diastereoselective and Enantioselective Intramolecular Amino-Zinc-Enolate Carbometalation Reactions. A New Polysubstituted Pyrrolidines Synthesis

Edwige Lorthiois, Ilan Marek and Jean-F. Normant
1998
J. Org. Chem. 1998, 63, 2442-2450

48) Amino-Zinc-Enolate Carbocyclization Reactions. New Access to Polysubstituted Piperidines Derivatives

Edwige Lorthiois, Ilan Marek and Jean-F. Normant
1998
J. Org. Chem. 1998, 64, 566-574

1997

47) Enantioselective Carbolithiation of β-alkylated Styrene

Stephanie Norsikian, Ilan Marek and Jean-F. Normant
1997
Tetrahedron Lett. 1997, 38, 7523-7526

46) Enantioselective Carbolithiation of Cinnamyl Acetals. New Access to Chiral disubstituted Cyclopropanes

Stephanie Norsikian, Ilan Marek, Jean-Francois Poisson and Jean-F. Normant
1997
J. Org. Chem. 1997, 62, 4898-4899

45) Zinca-Ene-Allene Cyclizations. A way to Substituted Tetrahydrofurans or Pyrrolidines

Edwige Lorthiois, Ilan Marek and Jean-F. Normant
1997
Bull. Soc. Chim. Fr. 1997, 134, 333-341

44) Zinca-En-Allene and Zinc-Enolate Cyclization. Towards the Synthesis of Polysubstituted Pyrrolidines

Edwige Lorthiois, Ilan Marek and Jean-F. Normant
1997
Tetrahedron Lett. 1997, 38, 89-92

43) A Simple and Convenient Method for the Preparation of (Z) or (E)-γ-Iodo Allylics Alcohols and (Z)-β-Iodo Acrolein

Ilan Marek, Christophe Meyer and Jean-F. Normant
1997
Org. Synth. 1997, 74, 194-204

1996

42) Synthesis and Reactivity of sp3 Geminated Organobismetallics

Ilan Marek and Jean-F. Normant
1996
Chem. Rev. 1996, 96, 3241-3267

41) Synthesis of Polysubstituted Stereodefined Olefins via the Reactivity of sp2 -Organogembismetallics

Isabelle Creton, Ilan Marek and Jean-F. Normant
1996
Synthesis 1996, 1499-1508

40) Intramolecular Carbolithiation of Silylated Enynes

Edwige Lorthiois, Ilan Marek and Jean-F. Normant
1996
Tetrahedron Lett. 1996, 37, 6693-6694

39) Intermolecular Carbolithiation of Silylated Enynes

Edwige Lorthiois, Ilan Marek, Christophe Meyer and Jean-F. Normant
1996
Tetrahedron Lett. 1996, 37, 6689-6692

38) Diastereoselective Carbometalation of δ-Mono and γ-λ-Disubstituted Z Vinyl Metals

Anja Bahr, Ilan Marek and Jean-F. Normant
1996
Tetrahedron Lett. 1996, 37, 5873-5876

37) Stereoselective Synthesis of Linear and Angular Triquinanes Skeletons via the Zinca-Ene Allene Reactions

Christophe Meyer, Ilan Marek and Jean-F. Normant
1996
Tetrahedron Lett. 1996, 37, 857-860

36) Diastereoselective Synthesis of Heterosubstituted Organogembismetallic Reagents. Application to a New Propargylmetalation Reaction of Vinyl Metals

Denis Brasseur, Ilan Marek and Jean-F. Normant
1996
Tetrahedron 1996, 52, 7235-7250

1995

35) Stereoselective Synthesis of Polysubstituted Olefins Via the Formation of 1,1-Bimetalloalkenes

Isabelle Creton, Ilan Marek and Jean-F. Normant
1995
Tetrahedron Lett. 1995, 36, 7451-7454

34) Asymmetric Carbolithiation of Cinnamyl Derivatives in the Presence of (-) Sparteine

Sophie Klein, Ilan Marek, Jean Francois Poisson and Jean-F. Normant
1995
J. Am. Chem. Soc. 1995, 117, 8853-8854

33) Diastereoselective Reactions of Gembismetallic Derivatives

Fan Wang, Jie Tang, Lydie Labaudiniere, Ilan Marek and Jean-F. Normant
1995
Synlett 1995, 723-7251

32) Metal-Alkene π-Chelation: A Stereodirecting Effect in Allylzincation Reactions and in Zinc Mediated Cyclopropanations

Ilan Marek, Dov Beruben and Jean-F. Normant
1995
Tetrahedron Lett. 1995, 36, 3695-3698

31) Stereodefined Substituted Cyclopropyl Zinc Reagents from Gembismetallics

Dov Beruben, Ilan Marek, Jean-F. Normant and Nicole Platzer
1995
J. Org. Chem. 1995, 60, 2488-2501

30) Zinca-En-Allene Cyclization. Synthesis of Substituted Tetrahydrofurans

Edwige Lorthiois, Ilan Marek, Christophe Meyer and Jean-F. Normant
1995
Tetrahedron Lett. 1995, 36, 1263-1266

29) Intramolecular Metallo-Ene-Allene Reactions. A New Carbocycles Synthesis

Christophe Meyer, Ilan Marek, Gilles Courtemanche and Jean-F. Normant
1995
J. Org. Chem. 1995, 60, 863-871

1994

28) Diastereoselective Carbometalation of -Heterosubstituted Vinylmetals

Ilan Marek, Jean-Michel Lefrancois and Jean-F. Normant
1994
Bull. Soc. Chim. Fr. 1994, 131, 910-918

27) Phenylthioacetylene as a Source of Stereodefined Trisubstituted Alkenes

Isabelle Creton, Ilan Marek, Denis Brasseur, Jean-Luc Jestin and Jean-F. Normant
1994
Tetrahedron Lett. 1994, 35, 6873-6876

26) Carbocyclization of -Acetylenic Propargylic Zinc Reagents

Christophe Meyer, Ilan Marek, Jean-F. Normant and Nicole Platzer
1994
Tetrahedron Lett. 1994, 35, 5645-5648

26) Carbocyclization of δ-Acetylenic Propargylic Zinc Reagents

Christophe Meyer, Ilan Marek, Jean-F. Normant and Nicole Platzer
1994
Tetrahedron Lett. 1994, 35, 5645-5648

25) Intramolecular Carbometallation of Organozinc Reagents

Christophe Meyer, Ilan Marek, Gilles Courtemanche and Jean-F. Normant
1994
Tetrahedron 1994, 50, 11665-11692

24) Diastereoselective Carbometalation of Vinyl Metals

Ilan Marek, Jean-Michel Lefrancois and Jean-F. Normant
1994
J. Org. Chem. 1994, 59, 4154-6166

23) Carbolithiation of Cinnamyldialkylamines. Stereochemistry of the Li to Zn transmetalation and Configurational Stability of Benzylic Organozinc Halides

Sophie Klein, Ilan Marek and Jean-F. Normant
1994
J. Org. Chem. 1994, 59, 2925-2926

1993

22) Cyclic Steocontrol Via Organobismetallic Reagents. Part VI. Stereodefined Substituted Cyclopropyl Zinc Reagents

Dov Beruben, Ilan Marek, Jean-F. Normant and Nicole Platzer
1993
Tetrahedron Lett. 1993, 34, 7575-7578

21) Intramolecular Carbometallation of Secondary Organozinc Reagents

Christophe Meyer, Ilan Marek, Gilles Courtemanche and Jean-F. Normant
1993
Tetrahedron Lett. 1993, 34, 6053-6056

20) Selective Monoalkylation of Organogembismetallics Via an Intramolecular Nucleophilic Substitution

Fabrice Chemla, Ilan Marek and Jean-F. Normant
1993
Synlett 1993, 665-666

19) (E)-or (Z)-β-Iodoacrolein: A Novel Versatile Synthon

Christophe Meyer, Ilan Marek and Jean-F. Normant
1993
Synlett 1993, 386-388

18) Carbocyclisation of Functionnalized Zinc Organometallics

Christophe Meyer, Ilan Marek and Jean-F. Normant
1993
Synlett 1993, 266-268

17) Cyclic Stereocontrol Via Organobismetallic Reagents. Part V. Diastereoselective Synthesis of Substituted Cyclopropyl Zinc Reagents by the Metalla-Claisen Reaction

Dov Beruben, Ilan Marek, Lydie Labaudiniere and Jean-F. Normant
1993
Tetrahedron Lett. 1993, 34, 2303-2306

1992

16) Resolution and Asymmetric Synthesis of Ortho-Substituted (Benzaldehyde) Tricarbonylchromium Complexes

Alex Alexakis, Pierre Mangeney, Ilan Marek, Francoise Rose-Munch, Eric Rose, Assia Semra and Francis Robert
1992
J. Am. Chem. Soc. 1992, 114, 8288-8290

15) Organobismetallic Zinc Reagents: Their Preparation and Use in Diastereoselective Reactions

Jean-F. Normant, Ilan Marek and Jean-Michel Lefrancois
1992
Pure and Appl. Chem. 1992, 64, 1857-1864

14) Acyclic Stereocontrol Via Organogembismetallic Reagents. Part III

Ilan Marek, Jean-Michel Lefrancois and Jean-F. Normant
1992
Synlett 1992, 633-634

13) Synthese d’Alcoxyallenes Chiraux par Carbocupration d’Acetals Propargyliques. Etude de leur Reactivite à l’Egard d’Organocuprates

Ilan Marek, Alex Alexakis, Pierre Mangeney and Jean-F. Normant
1992
Bull. Soc. Chem. Fr. 1992, 129, 171-190

12) Iodocyclisation of Olefinic t-Butyl Ethers: An Easy Stereocontrolled Synthesis of Cis-Substituted Tetrahydrofurans

Ilan Marek, Jean-Michel Lefrancois and Jean-F. Normant
1992
Tetrahedron Lett. 1992, 33, 1747-1748

1991

11) γ-Tributylstannyl-β-Metallated Acrolein: A Versatile Synthon

Ilan Marek, Alex Alexakis and Jean-F. Normant
1991
Tetrahedron Lett. 1991, 32, 6337-6340

10) Acyclic Stereocontrol through the Metalla-Claisen Rearrangement. Part II

Ilan Marek and Jean-F. Normant,
1991
Tetrahedron Lett. 1991, 32, 5973-5976

9) Acyclic Stereocontrol through the Metalla-Claisen Rearrangement. Part I

Ilan Marek, Jean-Michel Lefrancois and Jean-F. Normant
1991
Tetrahedron Lett. 1991, 32, 5969-5972

8) A Highly Efficient Synthesis of (Z)-γ-Iodo Allylic Alcohols

Ilan Marek, Alex Alexakis and Jean-F. Normant
1991
Tetrahedron Lett. 1991, 32, 5329-5332

7) Diastereoselective Syn or Anti Opening of Propargylic Epoxides. Synthesis of α-Allenic Alcohols

Alex Alexakis, Ilan Marek, Pierre Mangeney and Jean-F. Normant
1991
Tetrahedron 1991, 47, 1677-1696

1990

6) Mechanistic Aspects on the Formation of Chiral Allenes from propargylic Ethers and Organocopper Reagents

Alex Alexakis, Ilan Marek, Pierre Mangeney and Jean-F. Normant
1990
J. Am. Chem. Soc. 1990, 112, 8042-8047

5) Structure of 1,3,5-Triallyl-4,6-Diphenyl-1,3,5-Triazacyclohexan-2-one

Jean-P. Declercq and Ilan Marek
1990
Acta. Cryst. 1990, C46, 1168-1170

1989

4) Copper-Catalyzed Reductive Metallation of a Propargylic Epoxide to an Allenyl Lithium Reagent

Alex Alexakis, Ilan Marek, Pierre Mangeney and Jean-F. Normant
1989
Tetrahedron Lett. 1989, 30, 2391-2392

3) Diastereoselective Synthesis of α-Allenic Alcohols from Propargylic Epoxides

Alex Alexakis, Ilan Marek, Pierre Mangeney and Jean-F. Normant
1989
Tetrahedron Lett. 1989, 30, 2387-2390

1988

2) Chiral Acetals in Enantio-and Diastereoselective Substitution or Elimination Reactions

Alex Alexakis, Pierre Mangeney, Abdellaziz Ghribi, Ilan Marek, Richard Sedrani, Christophe Guir and Jean-F. Normant
1988
Pure & Appl. Chem. 1988, 60, 49-56

1986

1) Are Allenes Formed from Propargylic Ethers Through a Syn or Anti-Displacement?

Ilan Marek, Pierre Mangeney, Alex Alexakis and Jean-F. Normant
1986
Tetrahedron Lett. 1986, 27, 5499-5502