Articles
2023
278) Highly Diastereoselective Preparation of Tertiary Alkyl Thiocyanates en Route to Thiols by Stereoinvertive Nucleophilic Substitution at Nonclassical Carbocations
2023
Org. Lett. 2023, 25, 8474−8477
277) Oxenoids as Homologation Partners
2023
Homologation Reactions, Ed. Vittorio Pace, Wiley-VCH Weinheim, 2023, 287-308
276) Tetrazole Diversification of Amino Acids and Peptides via Silver-Catalyzed Intermolecular Cycloaddition with Aryldiazonium Salts
2023
Angew. Chem. Int. Ed. 2023, 62, e202304740
275) Selective Terminal Functionalization of Linear Alkanes
2023
Angew. Chem. Int. Ed. 2023, 62, e202306343
274) Dirhodium(II)-catalyzed enantioselective cyclopropenation of internal alkynes with trifluoromethyl carbene
2023
Chem Catalysis. 2023, 3, 100637
273) Highly Diastereoselective Preparation of Tertiary Alkyl Isonitriles by Stereoinvertive Nucleophilic Substitution at a Nonclassical Carbocation
2023
Org. Lett. 2023, 25, 2285–2288
272) Stereospecific Nucleophilic Substitution at Quaternary Carbon Stereocenters
2023
Chem, 2023, 9, 266-279
271) Stereoselective Construction of Tertiary Homoallyl Alcohols and Ethers by Nucleophilic Substitution at Quaternary Carbon Stereocenter
2023
Angew. Chem. Int. Ed. 2023, 62, e202212425
2022
270) Stereoselective Preparation of CF3-Containing Cyclopropanes
2022
Org. Lett. 2022, 24, 49, 9076–9080
269) Synthesis and Functionalization of Tertiary Propargylic Boronic Esters by Alkynyllithium-Mediated 1,2-Metalate Rearrangement of Borylated Cyclopropanes
2022
Org. Lett. 2022, 24, 8901−8906
268) Directed Diastereoselective Cyclopropanation and Epoxidation of Alkenyl Cyclopropyl Carbinols Derivatives
2022
Org. Lett. 2022, 24, 8322−8325
267) Regio- and Diastereoselective Carbometalation Reaction of Cyclopropenes
2022
Acc. Chem. Res. 2022, 55, 2848−2868
266) Stereoselective Synthesis of Polysubstituted Spiropentanes
2022
J. Am. Chem. Soc. 2022, 144, 16732–16736
265) Borylated Cyclopropanes as Spring-Loaded Entities: Access to Vicinal Tertiary and Quaternary Stereocenters in Acyclic Systems
2022
J. Am. Chem. Soc. 2022, 144, 16298−16302
264) Preparation of Distant Quaternary Carbon Stereocenters by Double Selective Ring-Opening of 1,1-Biscyclopropyl Methanol Derivatives
2022
Angew. Chem. Int. Ed. 2022, 61, e202203652
263) Stereoinvertive Nucleophilic Substitution at Quaternary Carbon Stereocenters of Cyclopropyl Ketones and Ethers
2022
Angew. Chem. Int. Ed. 2022, 61, e202203673
262) Stereospecific Construction of Quaternary Carbon Stereocenters from Quaternary Carbon Stereocenters
2022
J. Am. Chem. Soc. 2022, 144, 7066−7071
261) Mechanistic Insights on the Selectivity of the Tandem Heck-Ring-Opening of Cyclopropyldiol Derivatives
2022
JACS Au 2022, 2, 3, 687–696
260) Stereoselective Synthesis Through Remote Functionalization
2022
Nature Synthesis, 2022, 1, 37-48
2021
259) Stereodivergent Access to Trisubstituted Alkenylboronate Esters through Alkene Isomerization
2021
Org. Lett. 2021, 23, 9194−9198
258) Directed Regioselective Carbometallation of 1,2-Dialkyl-Substituted Cyclopropenes
2021
Angew. Chem. Int. Ed. 2021, 60, 26368–26372
257) Alkene Isomerization Revitalizes the Coates-Claisen Rearrangement
2021
Angew. Chem. Int. Ed. 2021, 60, 18509 –18513
256) Stereoselective Tandem Iridium-Catalyzed Alkene Isomerization-Cope Rearrangement of ω-diene Epoxides: Efficient Access to Acyclic 1,6-Dicarbonyl Compounds
2021
Chem. Sci. 2021, 12, 9328-9332
255) Stereoselective Sc(OTf)3‐Catalyzed Aldol Reactions of disubstituted Silyl Enol Ethers of Aldehydes with Acetals
2021
Angew. Chem. Int. Ed. 2021, 12765-12769
254) Regio‐ and Diastereoselective Copper‐Catalyzed Carbomagnesiation for the Synthesis of Penta‐ and Hexa‐Substituted Cyclopropanes
2021
Angew. Chem. Int. Ed. 2021, 60, 11804-11808
253) Creating Stereocenters within Acyclic Systems by C-C Bond Cleavage of Cyclopropanes
2021
Chem. Rev. 2021, 121, 1, 140-161
252) Carbon-Carbon Bond Cleavage in Stereoselective Synthesis
2021
Chem. Rev. 2021, 121, 1, 1–2.
2020
251) Remote Fluorination and Fluoroalkyl(thiol)ation Reactions
2020
Chem. Eur. J. 2020, 26, 15378-15396
250) Stereospecific Access to Allylboronic Esters Within Acyclic Systems Bearing Distant Tetrasubstituted Stereocenters
2020
Angew. Chem. Int. Ed. 2020, 59, 20434-20438
249) Stereospecific Nucleophilic Substitution at Tertiary and Quaternary Stereocentres
2020
Chem. Sci. 2020, 11, 9378-9385
248) Stereoselective Preparation of Distant Stereocenters (1,5) within Acyclic Molecules
2020
ACS Catal. 2020, 10, 7154−7161
247) Cobalt-Catalyzed Diastereoselective and Enantioselective Hydrosilylation of Achiral Cyclopropenes
2020
Org. Lett. 2020, 22, 4914−4918
246) Stereoselective Access to Fully Substituted Aldehyde‐Derived Silyl Enol Ethers by Iridium‐Catalyzed Alkene Isomerization
2020
Angew. Chem. Int. Ed. 2020, 59, 15549–15553
245) The Schulich Faculty of Chemistry, Technion –Israel Institute of Technology I. Marek, Y. Apeloig
2020
Eur. J. Org. Chem. (Editorial), 2020, 3116-3119
244) Construction of Acyclic Vicinal Tertiary and Quaternary Carbon Stereocenters via a Pd-Catalyzed Allylic Alkylation of Stereodefined Polysubstituted Ketene Aminals
2020
Eur. J. Org. Chem. 2020, 3133-3137
243) Ru-Catalyzed Isomerization of w-Alkenylboronates towards Stereoselective Synthesis of Vinylboronates with Subsequent in-situ Functionalization
2020
Chem. Sci. 2020, 11, 5944 - 5949
242) The protective effect of the TSPO ligands 2,4-Di-Cl-MGV-1, CB86, and 1 CB204 against LPS-induced M1 pro-inflammatory activation of microglia
2020
Brain, Behavior, & Immunity - Health 2020, 5, 100083
241) Alkene Isomerization through Allylmetals as a Strategic Tool in Stereoselective Synthesis
2020
ACS Catal. 2020, 10, 5793−5804
240) Nucleophilic Substitution at Quaternary Carbon Stereocenters
2020
J. Am. Chem. Soc. 2020, 142, 5543-5548 Corrections: J. Am. Chem. Soc. 2020, 142, 7710-7712
239) Pd-Catalyzed Enantioselective Hydroalkynylation of Cyclopropenes
2020
ACS Catal. 2020, 10, 1289-1293
238) Enantioselective Synthesis of Vicinal Tertiary and Quaternary Carbon Stereogenic Centers Within an Acyclic Chain
2020
Angew. Chem. Int. Ed. 2020, 59, 36-49
2019
237) Catalytic Enantioselective Cyclopropenation of Internal Alkynes: Access to Difluoromethylated Three-Membered Carbocycles
2019
Angew. Chem. Int. Ed. 2019, 58, 18191-18196
236) Diastereoselective Ring Opening of Fully-Substituted Cyclopropanes via Intramolecular Friedel–Crafts Alkylation
2019
Chem. Sci. 2019, 10, 9548-9554
235) Regio- and Stereoselective Synthesis of Fully Substituted Silyl Enol Ethers of Ketones and Aldehydes in Acyclic Systems.
2019
Angew. Chem. Int. Ed. 2019, 58, 14995-14999
234) Regio- and Diastereoselective Copper-Catalyzed Carbometalation of Cyclopropenylsilanes
2019
Org. Lett. 2019, 21, 9162-9165
233) Highly E-selective, Stereoconvergent Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling of Alkenyl Ethers
2019
Org. Lett. 2019, 21, 2913-2917
232) A Tandem Iridium-catalyzed ‘Chain-walking’/Cope Rearrangement Sequence
2019
ACS Catal. 2019, 9, 2400-2406
231) Diastereo- and Enantioselective Preparation of Cyclopropanol and Cyclopropylamine Derivatives
2019
Beilstein J. Org. Chem. 2019, 15, 752-760
230) Versatility in the Brook Rearrangement for Selective Ring-Opening of Three-Membered Rings Coralie Tugny, Fa-Guang Zhang and Ilan Marek
2019
Chem. Eur. J. 2019, 25, 205-209
2018
229) Convergent and Flexible Approach to Stereodefined Polyhydroxylated Fragments
2018
Tetrahedron (special issue for Prof. Leon Ghosez), 2018, 74, 6761-6768
228) Diastereoselective Ring Opening of Alkenylcyclopropanes: Application to the Total Synthesis of C30 Botryococcene and epi-Botryococcene
2018
Angew. Chem. Int. Ed. 2018, 58, 13237-13241.
227) Efficient and Stereodivergent Synthesis of Unsaturated Acyclic Fragments Bearing Contiguous Stereogenic Elements
2018
Nature Chem. 2018, 10, 1164-1170
226) Asymmetric Preparation of Polysubstituted Cyclopropanes Based on Direct Functionalization of Achiral Three-Membered Carbocycles
2018
Chem. Rev. 2018, 118, 8415-8434
225) Diastereo- and Enantioselective Copper Catalyzed Hydroallylation of Disubstituted Cyclopropenes
2018
Chem. Sci. 2018, 9, 6503-6508
224) Pd-Catalyzed Selective Remote Ring-Opening of Polysubstituted Cyclopropanols
2018
Chem. Eur. J. 2018, 24, 8553-8557
223) Metal-Catalyzed Remote Functionalization of -Ene Unsaturated Ethers as a New Entry to Functionalized Vinyl Species
2018
Angew. Chem. Int. Ed. 2018, 57, 57, 8012-8016
222) Asymmetric Rh-Catalyzed Arylation of Cyclopropenes Based on Directed Functionalization of Three-Membered Carbocycles (DFTMC)
2018
Angew. Chem. Int. Ed. 2018, 57, 3682-3686
221) Walking Metals for Remote Functionalization
2018
ACS Cent. Sci. 2018, 4, 153-165
220) Rosarium Philosophorum on Organic Synthesis
2018
Isr. J. Chem. 2018, 58, 122-126
219) Alkene-Zipper Catalyzed Selective and Remote Retro-Ene Reaction of Alkenyl Cyclopropylcarbinols
2018
Adv. Synth. Catal. 2018, 360, 1389-1396
218) Electrophilic Oxidation of Stereodefined Polysubstituted Silyl Ketene Aminals
2018
Eur. J. Org. Chem. 2018, 614-618
217) Electrophilic Fluorination of Stereodefined Polysubstituted Silyl Ketene Hemiaminals en route to Tertiary α-Fluorinated Carbonyl Derivatives
2018
Org. Biomol. Chem. 2018, 16, 1079-1082
216) Asymmetric Catalytic Preparation of Diastereo- and Enantiomerically Enriched Polysubstituted Cyclopropanol and Cyclopropylamine Derivatives
2018
Angew. Chem. Int. Ed. 2018, 57, 1543-1546
215) Zirconocene-Mediated Selective and Versatile C-C Bond Cleavage of Strained Carbocycles: Scope and Mechanism
2018
J. Org. Chem. 2018, 83, 3497-3515
2017
214) 2-Cl-MGV-1 Ameliorates Apoptosis in the Thalamus and Hippocampus and Cognitive Deficits after Cortical Infarct in Rats
2017
Stroke 2017, 48, 3366-3364
213) Tandem Hydroalumination/Cu-Catalyzed Asymmetric Vinyl Metalation as a New Access to Enantioenriched Vinylcyclopropane Derivatives.
2017
Org. Lett. 2017, 19, 3970-3973
212) Enantioselective Construction of Acyclic Quaternary Stereocenters: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Amide Enolates.
2017
J. Am. Chem. Soc. 2017, 139, 9615-9620
211) Classical and Novel TSPO Ligands for the Mitochondrial TSPO can Modulate Nuclear Gene Expression: Implications for Mitochondrial Retrograde Signaling.
2017
International Journal of Molecular Sciences 2017, 18, 786
210) Brook Rearrangement as a Trigger for the Formation of Carbene: Formation of Stereodefined Fully-Substituted Cyclobutene Derivatives.
2017
J. Am. Chem. Soc. 2017, 139, 8364-8370
209) Merging C-H and C-C Bonds Cleavage in Organic Synthesis
2017
Nature Rev. Chem. 2017, 1, 0035
208) Asymmetric Copper-Catalyzed Carbomagnesiation of Cyclopropenes.
2017
Angew. Chem. Int. Ed. 2017, 56, 6783-6787
207) Palladium-Catalyzed Oxidative Cyclization of Aniline-Tethered Alkylidenecyclopropanes with O₂; A Facile Protocol to Selectively Synthesize 2- and 3-Vinylindoles.
2017
Chem. Commun. 2017, 53, 216-219
206) A Unique Pd-Catalyzed Heck Arylation as a Remote Trigger for Cyclopropane Selective Ring-Opening
2017
Nature Comm. 2017, 8, 14200
205) Enantioselective Allylic Alkylation of Stereodefined Polysubstituted Copper Enolates as an Entry to Acyclic Quaternary Carbon Stereocentre
2017
Chem. Sci. 2017, 8, 627-630
204) Diastereoselective Carbometalation of Cyclobutenes
2017
Chem. Sci. 2017, 8, 334-339
2016
203) Zirconocene-Assisted Remote Cleavage of C-C and C-O Bonds: Application to Acyclic Stereodefined Metalated Hydrocarbons
2016
Org. Biomol. Chem., 2016, 14, 10325-10330
202) Formation of Carbon Quaternary Stereogenic Center in Acyclic Systems via a Sequence of Carbometalation − Intramolecular Cyclization − Silicon Activation
2016
Synthesis 2016, 48, 3279-3286
201) Oxidation of bis-Sulfinyl Carbanion as the Pivot of Ionic/Radical Tandem Reactions
2016
Compte Rendu Academie des Sciences 2016, 19, 403-411
200) Preparation and Reactivity of Acyclic Chiral Allylzinc Species via a Zn-Brook Rearrangement
2016
Angew. Chem. Int. Ed. 2016, 55, 6057-6061
199) Diastereodivergent Combined Carbometalation − Zinc Homologation – C-C Fragmentation Reaction as an Efficient Tool to Prepare Acyclic Allylic Quaternary Carbon Stereocenters
2016
Chem. Sci. 2016, 7, 5989-5994
198) Brook Rearrangement as a Trigger for Ring-Opening strained Carbocycles
2016
Angew. Chem. Int. Ed. 2016, 55, 714-718
197) Stereoselective Formation of Trisubstituted Ketone Enolates
2016
Angew. Chem. Int. Ed. 2016, 55, 5517-5520
195) Copper mediated carbometalation reactions
2016
Chem. Soc. Rev. 2016, 45, 4552-4566
194) Merging Allylic C-H Bond Activation and C-C Bond Cleavage en route to the Formation of Quaternary Carbon stereocenter in Acyclic Systems
2016
Nature Protocols 2016, 12, 74-87
2015
193) Asymmetric Copper-Catalyzed Carbozincation of Cyclopropenes en route to the Formation of Diastereo- and Enantiomerically Enriched Polysubstituted Cyclopropanes
2015
J. Am. Chem. Soc. 2015, 137, 15414-15417
191) The Scientific Bridge: Fifty Years of Germany-Israel Diplomatic Relations
2015
Angew. Chem. Int. Ed. 2015, 51, 12182-12183
190) Quinazoline-Based Tricyclic Compounds that Regulate Programmed Cell Death, Induce Neuronal Differentiation, and are Curative in Animal Models for Excitoxicity and Hereditary Brain Disease
2015
Cell Death Discovery 2015, 1, 15027
189) Stereodefined Acyclic Trisubstituted Silyl Enol Ethers Towards the Asymmetric Formation of Aldol Products Possessing Quaternary Carbon Stereocenters
2015
Angew. Chem. Int. Ed. 2015, 54, 14933-14937
188) Gold(I)-Catalyzed Cycloisomerization of Vinylidenecyclopropane-enes via Carbene or non-Carbene Processes
2015
Chem. Sci. 2015, 6, 5519-5525
187) Forming Stereogenic Centers in Acyclic Systems from Alkynes
2015
Angew. Chem. Int. Ed. 2015, 54, 9996-999
186) Probing the Limits of NMR and VCD Spectroscopies in the Stereochemical Assignment of Chiral ²H₆-Neopentane
2015
Angew. Chem. Int. Ed. 2015, 54, 13106-13109
185) Formation of Several Carbon-Carbon Bonds in Acyclic Systems
2015
Chem. Rev. 2015, 115, 9175-9206
184) Cyclopropene Derivatives as a New Entry to Enantioenriched Cyclopropanol and n-Butenal Possessing Quaternary Carbon Stereocenters
2015
Angew. Chem. Int. Ed. 2015, 54, 12345-12348
183) Remote Functionalization of Hydrocarbons with Reversibility Enhanced Stereocontrol
2015
Chem. Sci. 2015, 6, 2770-2776
182) Gold and Silver-Catalyzed Intramolecular Cyclizations of Indolylcyclopropenes for the Divergent Synthesis of Azepinoindoles and Spiroindoline Piperidines
2015
ChemCatChem 2015, 7, 595-600
181) Selective Carbon-Carbon Bond Cleavage for the Stereoselective Synthesis of Acyclic Systems
2015
Angew. Chem. Int. Ed. 2015, 54, 414-429
180) Electrophilic Amination: The Case of Nitrenoids
2015
Chem. Eur. J. 2015, 14, 5278-5300
2014
179) Formation of Three New Bonds and Two Stereocenters in Acyclic Systems by Zinc-Mediated Asymmetric Alkynylation of Acylsilanes, Brook Rearrangement and Ene-Allene Carbocyclization Reactions
2014
J. Org. Chem. 2014, 79, 12122-12135
178) Stereodefined Acyclic Trisubstituted Metal Enolates Towards the Asymmetric Formation of Quaternary Carbon Stereocentres
2014
Chem. Comm. 2014, 50, 12597- 12611
177) Isoxazole-Embedded Allylic Zinc Reagent for the Diastereoselective Preparation of Highly Functionalized Aldol-Type derivatives Bearing a Stereocontrolled Quaternary Center
2014
Chem.-Eur. J. 2014, 20, 20, 14096-14101
176) Chemistry in Israel−at a Crossroads? (Editorial)
2014
Angew. Chem. Int. Ed. 2014, 53, 3754-3755
175) All-Carbon Quaternary Stereogenic Centers in Acyclic System through the Creation of Several C-C bonds per Chemical Steps
2014
J. Am. Chem. Soc. 2014, 136, 2682-2694
174) Highly Diastereoselective Preparation of Aldol Products Using New Functionalized Allylic Aluminum Reagents
2014
Org. Lett. 2014, 16, 956-959
172) Advances in Carbolithiation
2014
In Lithium Compounds in organic Synthesis: From Fundamentals to Applications, First Edition. Edited by Renzo Luisi and Vito Capriati. Wiley-VCH 2014, 329-350
171) Carbometalation Reactions
2014
In Copper-catalyzed Asymmetric Synthesis, First Edition. Edited by Alexandre Alexakis, Norbert Krause and S. Woodward. Wiley-VCH, 2014, 267-282.
170) Merging Allylic C-H Activation and Selective C-C Bond Activation
2014
Nature 2014 505, 199-203
169) Modulable and Highly Diastereoselective Carbometalations of Cyclopropenes
2014
Chem. Eur. J. 2014, 20, 1038-1048
168) Carbometalation Reactions
2014
Eds de Meijere, A., Oestreich, M., Brase, S. Wiley-VCH,2014, 769-
2013
167) A One-Pot Zinc-promoted Asymmetric Alkynylation/Brook-Type Rearrangement/Ene-Allene Cyclization: Highly Selective Formation of Three New bonds and two Stereocenters in Acyclic Systems
2013
Angew. Chem. Int. Ed. 2013, 52, 13717-13721
166) Carboxylate-Assistance for Catalyzed Hydroarylations of Methylenecyclopropanes
2013
Org. Lett. 2013, 15, 4482-4484
165) Stereodefined Trisubstituted Enolates as a Unique Entry to All-Carbon Quaternary Stereogenic Centres in Acyclic Systems
2013
Nature Protocols 2013, 4, 749-754
164) Axial Preferences in Allylation Reactions via the Zimmerman – Traxler Transition State
2013
Acc. Chem. Res. 2013, 46, 1659-1669
163) Regio- and Stereoselective Carbometallation Reactions of N-Alkynyl-Amides and Sulfonamides
2013
Beilstein J. Org. Chem. 2013, 9, 526-532.
162) The Renaissance of Zinc Carbenoid in Stereoselective Synthesis in Acyclic systems
2013
Organometallics 2013, 32, 942-950
161) Diastereodivergent Carbometalation/Oxidation/Selective Ring Opening: Formation of All‐Carbon Quaternary Stereogenic Centers in Acyclic Systems†
2013
Angew. Chem. Int. Ed. 2013, 52, 5333-5337
160) Carboxylate-assisted Ruthenium(II)-Catalyzed C-H Arylation of 5-Aryl Tetrazoles: Step-Economical Access to Valsartan
2013
Tetrahedron 2013, 69, 4445-4453
159) New Advances in Bis(sulfoxides) Chemistry
2013
Phosphorus Silicon & Related 2013, 188, 367-376
158) Carboxylate-Assisted Ruthenium(II)-Catalyzed Hydroarylations of Unactivated Alkenes via C–H Cleavage
2013
Angew. Chem. Int. Ed. 2013, 52, 3977-3980
2012
157) Alkenyl Zinc Reagents in Cross-Coupling Reactions In Cross-Coupling and Heck-Type Reactions 1 − C-C Cross Coupling Using Organometallic Partners
2012
Science of Synthesis 2012, 765-794
156) Forming All-Carbon Quaternary Stereogenic Centres in Acyclic Systems from Alkynes
2012
Nature 2012, 490, 522
155) Convergent Diastereoselective Preparation of Adjacent Quaternary Stereocenters in an Acyclic System
2012
Org. Biomol. Chem., 2012, 10, 5803-5806 (Special issue for 10th Birthday)
2011
154) Efficient Brønsted Acid Catalyzed Hydrations and Hydroaminations of (Dicyclopropylmethylene) cyclopropane
2011
Synlett 2011, 1515-1518
153) Combined Carbometalation–Zinc Homologation–Allylation Reactions as a New Approach for Alkoxyallylation of Aldehyde
2011
Org. Lett. 2011, 13, 3604-3607
152) Conjugate Additions to Alkylidene Bis-sulfoxides
2011
Chem. Asian J. 2011, 6, 1825-1833
151) Axial Preferences in Allylation via the Zimmerman-Traxler Transition State
2011
Chem. Eur. J. 2011, 17, 8000-800
150) Carbometalation of Carbon-Carbon Double Bonds in Stereoselective Carbometalation of Carbon-Carbon Double Bonds
2011
Stereoselective Synthesis 1 in Science of Synthesis Ed: J. G. de Vries, 2011, 325-408
149) Enantioselective Synthesis of all-Carbon Quaternary Stereogenic Centers in Acyclic Systems
2011
Chem. Commun. (Feature article) 2011, 47, 4593-4623
147) Regioselective Carbon-Carbon Bond Cleavage in the Oxidation of Cyclopropenylcarbinols
2011
Org. Lett. 2011, 13, 4076-4079
2010
148) Recent Advances in Carbocupration of α-Heterosubstituted Alkynes
2010
Beilstein J. Org. Chem. 2010, 6, No. 77. doi:10.3762/bjoc.6.77
146) Selectivity in Metal-Catalyzed Carbon-Carbon Bond Cleavage of Alkylidenecyclopropanes
2010
Chem. Eur. J. 2010, 16, 9712-9721
145) Diastereo- and Enantioselective Intramolecular Carbometalation Reaction
2010
Tetrahedron 2010, 66, 4874-4881
144) Highly Diastereoselective Preparation of Homoallylic Alcohols Containing Two Contiguous Quaternary Stereocenters in Acyclic Systems from Simple Terminal Alkynes
2010
J. Am. Chem. Soc. 2010, 132, 5588-5589
143) Hydroformylation Reaction of Alkylidenecyclopropane Derivatives: A new Pathway for the Formation of Acyclic Aldehydes Containing Quaternary Stereogenic Carbons
2010
J. Am. Chem. Soc. 2010, 132, 4066-4067
142) The Superiority of Properly Prepared Lithium 1-N,N-Dimethylaminonaphthalenide (LDMAN) over Other Aromatic Radical-anions for the Generation of Organolithiums by Reductive Lithiation
2010
Tetrahedron Lett. 2010, 51, 174-176
141) Regiodivergent Carbometalation Reactions of Ynol Ether Derivatives
2010
Synlett 2010, 329.
140) Metal-Catalyzed Ring-Opening of Alkylidenecyclopropanes as a New Approach to the Preparation of Enantiomerically Pure all-Carbon Quaternary Stereocenters
2010
Chem. Eur. J. 2010, 16, 774.
2009
139) Enantioselective Preparation of Enantiomerically Pure Cyclobutene Derivatives
2009
Chem. Commun. 2009, 5760-5762
138) Preface for a special issue of Chemistry, A European Journal dedicated to Yitzhak Apeloig
2009
Chem. Commun. 2009, 5760-5762
137) Cyclopropenylcarbinol Derivatives: New Versatile Intermediates in Organic Synthesis. Application to the Formation of Enantiomerically Pure Alkylidenecyclopropane Derivatives.
2009
Chem. Eur. J. 2009, 15, 8449-8464
135) Tandem Zn-Brook Rearrangement/Ene-Allene Carbocyclization
2009
Eur. J. Org. Chem. 2009, 1749-1756
134) Enantioselective Construction of all-Carbon Quaternary Stereogenic Carbons in Aldol Reactions
2009
Nature Chemistry, 2009, 1, 128-132
133) Diastereo- and Enantioselective Zinc Ene-Allene Carbocyclization
2009
Org. Lett. 2009, 11, 1853-1856
132) Copper-Catalyzed Hydride Transfer Towards the Formation of Alkylidenecyclopropane Derivatives
2009
Chem. Commun. 2009, 292-294
131) Stereoselective Synthesis of Metalated Cyclobutane Derivatives
2009
Advanced Synthesis and Catalysis 2009, 351, 1005-1008
2008
130) Zinc Homologation-Elimination Reaction of α-Sulfinyl Carbanions as a New Route to Olefins
2008
Eur. J. Org. Chem. (2008) 4924-4931
129) Zinc Homologation-Elimination Reaction of α-Sulfinyl Carbanions as a New Route to Olefins
2008
Eur. J. Org. Chem. 2008, 4924-4931
128) Convergent Preparation of Enantiomerically Pure Polyalkylated Cyclopropane Derivatives
2008
Angew. Chem. Int. Ed. 2008, 47, 6865-6868
127) A Shift in Retrosynthetic Paradigm (Concept article)
2008
Chem. Eur. J. 2008, 14, 7460-7468
126) Cyclopropenyllithiums as a New Source of 1,1-Bismetalated Cyclopropyl Derivatives
2008
Chem. Commun. 2008, 4300
125) Synthesis of Sulfoximidoyl-Substituted Triazoles by Huisgen 1,3-Dipolar Cycloaddition
2008
Synlett 2008, 116-118
2007
124) Intramolecular Carbozincation of Unactivated Alkenes Occurs Through a Zinc Radical Transfer Mechanism
2007
J. Am. Chem. Soc. 2007, 129, 15405-15409
123) Diastereodivergent Synthesis of Enantiomerically Pure Homoallylic Amine Derivatives Containing Quaternary Carbon Stereocenters
2007
Angew. Chem. Int. Ed. 2007, 46, 9291-9294
122) An Efficient, Facile and General Stereoselective Preparation of Heterosubstituted Alkylidenecyclopropanes
2007
Angew. Chem. Int. Ed. 2007, 46, 8039-8042
121) Enantiomerically Enriched Cyclopropene Derivatives: Versatile Building Blocks in Asymmetric Synthesis
2007
Angew. Chem. Int. Ed. 2007, 46, 7364-7376; (Corrigenda Angew. Chem. Int. Ed. 2008, 47, 1982)
120) Creation of Chiral Quaternary Stereocenters in the Carbonyl Allylation Reactions
2007
Chem. Commun. (Feature article), 2007, 43, 1683-1691
119) Stereodivergent Carbometalation Reactions of Cyclopropenylcarbinols Derivatives
2007
Org. Lett. 2007, 9, 2569-2571
118) Regio- and Stereoselective Copper-Catalyzed Carbozincation of Alkynylsulfoximines
2007
Org. Lett. 2007, 9, 1259-1261
2006
117) A Zirconium Promenade; A Efficient Tool in organic Synthesis
2006
Synlett (account), 2006, 501-514
116) Multicomponent Approach for the Creation of Chiral Quaternary Centers in the Carbonyl Allylation Reactions
2006
J. Am. Chem. Soc. 2006, 128, 4642-4649
115) Chiral Cyclopropenylcarbinols as a New Source of Chiral Alkylidenecyclopropane Derivatives
2006
Angew. Chem. Int. Ed. 2006, 45, 3963-3965
114) Unsaturated Fatty Alcohol Derivatives as a New Source of Substituted Allylzirconocenes
2006
Angew. Chem. Int. Ed. 2006, 45, 465-468
2005
113) New Tandem Zn-Promoted Brook Rearrangement/Ene-Allene carbocyclization Reactions
2005
Org. Lett. 2005, 7, 5313-5316
112) Special issue of Tetrahedron Symposium-in-Print on Multicomponent Reactions
2005
Tetrahedron, 2005, 61, 11309-11519. Guest Editors
111) Stereoselective Functionalization of Cyclopropane Derivatives Using Bromine/Magnesium and Sulfoxide/Magnesium Exchange Reactions
2005
Org. Lett. 2005, 7, 3789-3791
110) Preparation and Synthetic Transformation of Alkenyl Carbamate into Vinyl Zirconocene Derivatives
2005
Synthesis 2005, 3311-3318
109) Functionalized Organozirconium and Titanium in Organic Synthesis In Functionalized Organometallic Derivatives
2005
Ed. P. Knochel, Wiley-VCH, Weinheim, 2005, 503-540
108) Regiocontrolled Carbometallation Reactions of Ynamides
2005
Synlett 2005, 2098-2100
107) Synthesis of Chiral Methylenecyclopropanes Derivatives
2005
Synlett 2005, 2239-2241
2004
106) Ambiphilic Zinc Carbenoid as a New Tool for Multicomponent Condensation Reactions
2004
Isr. Chem. Soc. 2004, 16, 22-32
105) Stereoselective Synthesis and Reactivity of Dienyl Zirconocene
2004
Practical Synthetic Procedures Synthesis, 2004, 2411-2417
104) New Regio-, Stereo-, Diastereo-, and Enantioselective One-Pot Reactions Mediated by Organometallic Derivatives
2004
Synthesis 2004, 2411-2417
103) Functionalized Organozirconium and Titanium in Organic Synthesis In Functionalized Organometallic Derivatives
2004
Springer Verlag, 2004, 133-166
102) The Preparation of Organolithium Compounds and Derivatives in The Chemistry of Organolithium Compounds
2004
Eds Rappoport, Z.; Marek, I., John Wiley & Sons, Chichester, 2004, 435-493
101) Carbometallation Reaction in Transition Metals for Fine Chemicals and Organic Synthesis-second edition
2004
Eds C. Bolm, M. Beller, Wiley-VCH, 2004, 563-573
100) Carbometalation Reaction in Metal-Catalyzed Cross-Coupling Reactions- second edition
2004
Eds F. Diederich, A. de Meijere Wiley-VCH, 2004, 395-478
99) Stereoselective Preparation of Deuteriated Dienes by Ring Fragmentation of Metallated Cyclopropylcarbinols
2004
Synlett 2004, 1288-1290
98) Convenient Access to 2-(Trialkylstannyl)cyclopropylamines and Their Application in Palladium-Catalyzed Cross-Coupling Reactions
2004
Eur. J. Org. Chem. 2004, 631-635
97) Diastereoselective Reduction of Cyclopropenylcarbinol: new Access to Anti-Cyclopropylcarbinol Derivatives
2004
Org. Lett. 2004, 6, 341-343
96) α-Sulfinyl Carbanions as a New Source of Olefins
2004
Org. Lett. 2004, 6, 621-623
95) From Vinyl Sulfides, Sulfoxides and Sulfones to Vinyl Zirconocene Derivatives
2004
Tetrahedron 2004, 60, 1329-1337
2003
94) Regio- and Stereoselective Synthesis of Novel E-Alkenyl Carbamate via Carbocupration Reaction
2003
Org. Lett. 2003, 5, 5087-5089
93) Stereoselective Preparation of Dienyl Zirconocene Complexes via a Tandem Allylic C-H bond Activation-Elimination Sequence
2003
J. Am. Chem. Soc. 2003, 125, 13258-13264
92) Four-Component Reactions for a New Diastereo- and Enantioselective Synthesis of Chiral Quaternary Centers.
2003
J. Am. Chem. Soc. 2003, 125, 11776-11777
91) Synthesis and Reactivity of Geminated Organobismetallic Derivatives
2003
Actualite Chimique, special issue on the Present and future in Chemistry, 2003, 17-24
90) Stereoselective Preparation of Functionalized Unsaturated Lactones and Esters via Functionalized Magnesium Compounds
2003
Synthesis 2003, 1797-1802
89) Reaction of Allylzirconocene Compounds with Isolated or In Situ Generated η⁵ Pentadienyl Fe(CO)₃ /Fe(CO)₂ PPh₃(+1) Cations.
2003
Tetrahedron Lett. 2003, 44, 5909-5912
2002
88) Sp3 Organozinc Carbenoid Homologation in Organic Synthesis
2002
Tetrahedron Report, 2002, 58, 9463-9475
87) New Approach to the Stereoselective Synthesis of Metallated Dienes via an Isomerization-Elimination Sequence
2002
J. Am. Chem. Soc. 2002, 124, 10282-10283
87) New Approach to the Stereoselective Synthesis of Metallated Dienes via an Isomerization-Elimination Sequence
2002
J. Am. Chem. Soc. 2002, 124, 10282-10283
86) New Preparation of Stereodefined α,β-Unsaturated Ketones by Carbomagnesiation of allenyl ketone
2002
Tetrahedron Lett. 2002, 43, 6009-6010
85) New Methods for the Preparation of Sp2 Organometallic derivatives
2002
Synthesis 2002, 2473-2483
84) Carbocupration-Zinc Carbenoids Homologation and β-Elimination Reactions for a New Synthesis of Allenes. Applications to a New Synthesis of Chiral Allenes via Deracemization of Sp3 Organometallic Derivatives
2002
Eur. J. Org. Chem. 2002, 4151-4158
83) Diastereoselective Reduction of Alkenylboronic Esters as a New Method for Controlling the Stereochemistry of up to Three Adjacent Centers and Acyclic Molecules
2002
Org. Lett. 2002, 4, 2861-2863
82) Functionalized Aminocyclopropanes from Functionalized Organozinc Compounds and N,N Dialkylcarboxamides
2002
Synlett 2002, 879-882
81) Catalytic Asymmetric and Stereoselective Synthesis of Vinyl Cyclopropanes
2002
Synlett 2002, 423-426
80) From Vinyl Sulfides, Sulfoxides and Sulfones to Transition Metal Complexes k
2002
Angew. Chem. Int. Ed. 2002, 41, 1410-1413
79) Preparation of New Functionalized Cyclopropylmagnesium Reagents
2002
Angew. Chem. Int. Ed. 2002, 41, 351-352
2001
78) Preface for a special issue of the Journal of Organometallic Chemistry dedicated to Prof. Jean-F. Normant
2001
J. Organomet. Chem. 2001, 624, 1-3
77) Oxidative Addition-β-Elimination: A New Method for the Preparation of Organometallic Compounds
2001
J. Organomet. Chem. 2001, 624, 26-33
76) Diastereoselective Carbozincation of Propargylic Amines
2001
Tetrahedron 2001, 57, 2477-2483
75) Improved Preparation of Secondary Zinc Iodides by 1,2-Migration of sp3 Carbenoids
2001
Synlett 2001, 818-820
2000
74) Synthesis and Reactivity of sp2 Geminated Organobismetallics
2000
Chem. Rev. 2000, 100, 2887-2900
73) Carbometalation of Unactivated Alkynes via Low Valent Titanium Derivatives
2000
Chem. Commun. 2000, 1849-1850
72) New Allene Synthesis via Carbocupration- Zinc Carbenoid Homologation and β-Elimination
2000
Org. Lett. 2000, 2, 2849-2852
71) Stereoselective Preparation of E-Vinyl Zirconium Derivatives from E or Z-Enol Ether
2000
J. Org. Chem. 2000, 65, 7518-7220
70) First Synthesis and Reactivity of Functionalized Alkynyl Titanium Derivatives.
2000
Synthesis 2000, 917-920
69) Novel Stereoselective and Enantioselective Synthesis of Heterocyclic Compounds by Anionic Method
2000
Actual. Chim. 2000, 3, 60-61
68) Synthesis and Reactivity of Polymetallated Olefins and Functionalized Metallo-Alkynes
2000
Polyhedron 2000, 19, 563-566
66) Fluoroform: An Efficient Precursor for the Trifluoromethylation of Aldehydes
2000
Tetrahedron 2000, 56, 275-283
1999
65) Enantioselective Carbometalation of Unactivated Olefins
1999
J. Chem. Soc. Perkin Trans. 1, 1999, 535-544
64) Iodine Transfer Cyclization Mediated by DIBAL-H/THF
1999
Chem. Commun. 1999, 2375-2376
63) A New Approach Towards the Synthesis of sp3 1,1-Diiodoalkanes
1999
Chem. Commun. 1999, 2207-2208
62) First Synthesis of Metallated Titanacyclopropenes
1999
Synlett 1999, 11, 1939-1941
61) Preparation and Reaction of Functionalized Magnesium Carbenoids
1999
Synlett 1999, 11, 1820-1822
60) The Allyl Zincation of Vinyl Metals. A Computational Study
1999
Org. Lett. 1, 1999, 929-931
59) Enantioselective Carbometalation of Cinnamyl Derivatives: New Access to Chiral Disubstituted Cyclopropanes. Configurational Stability of Benzylic Organozinc Halides
1999
Chem. Eur. J. 1999, 5, 2055
58) Diastereoselective contra-Michael addition of (-)-sparteine/organolithium complexes to secondary chiral cinnamyl amides
1999
Tetrahedron Lett. 1999, 40, 3383-3386
57) Regioselective Addition of n-Butyllithium on Secondary Cinnamyl Amides Michael versus Contra-Michael Process
1999
Tetrahedron Lett. 1999, 40, 3379-3382
56) First Transfer of Chirality in the Fritsch- Buttenberg-Wiechell Rearrangement, via Zinc Carbenoids: A Migration with Retention of Configuration
1999
Tetrahedron Lett. 1999, 40, 1899-1902
1998
55) Preparation and Reaction of 1,n-bimetallic Reagents in Practical Approach in Organozinc Chemistry
1998
Ed. Knochel, P. Oxford University Press, 1998, 119-137
54) Carbometallation Reactions in Metal-Catalyzed Cross-Coupling Reactions
1998
Eds Stang, P.J., Diederich, F. Wiley-VCH, 1998, 271-337
53) Carbometalation Reactions in Transition Metals for Fine Chemicals and Organic Synthesis,
1998
Eds. Bolm, C., Beller, C. Wiley-VCH, 1998, 514-522
52) Diastereoselective Carbometalation of Chiral Vinyl Metals
1998
C. R. Acad. Sci. Paris, t.1, Serie II c 1998, 621-625
51) First Diastereoselective Carbometalation of Chiral Vinyl Metals
1998
Tetrahedron Lett. 1998, 39, 4821-4824
50) Fluoroform: An Efficient Precursor for the Trifluoromethylation of Carbonyl Compounds
1998
Tetrahedron Lett. 1998, 39, 2973-2976
49) Diastereoselective and Enantioselective Intramolecular Amino-Zinc-Enolate Carbometalation Reactions. A New Polysubstituted Pyrrolidines Synthesis
1998
J. Org. Chem. 1998, 63, 2442-2450
48) Amino-Zinc-Enolate Carbocyclization Reactions. New Access to Polysubstituted Piperidines Derivatives
1998
J. Org. Chem. 1998, 64, 566-574
1997
47) Enantioselective Carbolithiation of β-alkylated Styrene
1997
Tetrahedron Lett. 1997, 38, 7523-7526
46) Enantioselective Carbolithiation of Cinnamyl Acetals. New Access to Chiral disubstituted Cyclopropanes
1997
J. Org. Chem. 1997, 62, 4898-4899
45) Zinca-Ene-Allene Cyclizations. A way to Substituted Tetrahydrofurans or Pyrrolidines
1997
Bull. Soc. Chim. Fr. 1997, 134, 333-341
44) Zinca-En-Allene and Zinc-Enolate Cyclization. Towards the Synthesis of Polysubstituted Pyrrolidines
1997
Tetrahedron Lett. 1997, 38, 89-92
43) A Simple and Convenient Method for the Preparation of (Z) or (E)-γ-Iodo Allylics Alcohols and (Z)-β-Iodo Acrolein
1997
Org. Synth. 1997, 74, 194-204
1996
42) Synthesis and Reactivity of sp3 Geminated Organobismetallics
1996
Chem. Rev. 1996, 96, 3241-3267
41) Synthesis of Polysubstituted Stereodefined Olefins via the Reactivity of sp2 -Organogembismetallics
1996
Synthesis 1996, 1499-1508
40) Intramolecular Carbolithiation of Silylated Enynes
1996
Tetrahedron Lett. 1996, 37, 6693-6694
39) Intermolecular Carbolithiation of Silylated Enynes
1996
Tetrahedron Lett. 1996, 37, 6689-6692
38) Diastereoselective Carbometalation of δ-Mono and γ-λ-Disubstituted Z Vinyl Metals
1996
Tetrahedron Lett. 1996, 37, 5873-5876
37) Stereoselective Synthesis of Linear and Angular Triquinanes Skeletons via the Zinca-Ene Allene Reactions
1996
Tetrahedron Lett. 1996, 37, 857-860
36) Diastereoselective Synthesis of Heterosubstituted Organogembismetallic Reagents. Application to a New Propargylmetalation Reaction of Vinyl Metals
1996
Tetrahedron 1996, 52, 7235-7250
1995
35) Stereoselective Synthesis of Polysubstituted Olefins Via the Formation of 1,1-Bimetalloalkenes
1995
Tetrahedron Lett. 1995, 36, 7451-7454
34) Asymmetric Carbolithiation of Cinnamyl Derivatives in the Presence of (-) Sparteine
1995
J. Am. Chem. Soc. 1995, 117, 8853-8854
33) Diastereoselective Reactions of Gembismetallic Derivatives
1995
Synlett 1995, 723-7251
32) Metal-Alkene π-Chelation: A Stereodirecting Effect in Allylzincation Reactions and in Zinc Mediated Cyclopropanations
1995
Tetrahedron Lett. 1995, 36, 3695-3698
31) Stereodefined Substituted Cyclopropyl Zinc Reagents from Gembismetallics
1995
J. Org. Chem. 1995, 60, 2488-2501
30) Zinca-En-Allene Cyclization. Synthesis of Substituted Tetrahydrofurans
1995
Tetrahedron Lett. 1995, 36, 1263-1266
29) Intramolecular Metallo-Ene-Allene Reactions. A New Carbocycles Synthesis
1995
J. Org. Chem. 1995, 60, 863-871
1994
28) Diastereoselective Carbometalation of -Heterosubstituted Vinylmetals
1994
Bull. Soc. Chim. Fr. 1994, 131, 910-918
27) Phenylthioacetylene as a Source of Stereodefined Trisubstituted Alkenes
1994
Tetrahedron Lett. 1994, 35, 6873-6876
26) Carbocyclization of δ-Acetylenic Propargylic Zinc Reagents
1994
Tetrahedron Lett. 1994, 35, 5645-5648
25) Intramolecular Carbometallation of Organozinc Reagents
1994
Tetrahedron 1994, 50, 11665-11692
24) Diastereoselective Carbometalation of Vinyl Metals
1994
J. Org. Chem. 1994, 59, 4154-6166
23) Carbolithiation of Cinnamyldialkylamines. Stereochemistry of the Li to Zn transmetalation and Configurational Stability of Benzylic Organozinc Halides
1994
J. Org. Chem. 1994, 59, 2925-2926
1993
22) Cyclic Steocontrol Via Organobismetallic Reagents. Part VI. Stereodefined Substituted Cyclopropyl Zinc Reagents
1993
Tetrahedron Lett. 1993, 34, 7575-7578
21) Intramolecular Carbometallation of Secondary Organozinc Reagents
1993
Tetrahedron Lett. 1993, 34, 6053-6056
20) Selective Monoalkylation of Organogembismetallics Via an Intramolecular Nucleophilic Substitution
1993
Synlett 1993, 665-666
18) Carbocyclisation of Functionnalized Zinc Organometallics
1993
Synlett 1993, 266-268
17) Cyclic Stereocontrol Via Organobismetallic Reagents. Part V. Diastereoselective Synthesis of Substituted Cyclopropyl Zinc Reagents by the Metalla-Claisen Reaction
1993
Tetrahedron Lett. 1993, 34, 2303-2306
1992
16) Resolution and Asymmetric Synthesis of Ortho-Substituted (Benzaldehyde) Tricarbonylchromium Complexes
1992
J. Am. Chem. Soc. 1992, 114, 8288-8290
15) Organobismetallic Zinc Reagents: Their Preparation and Use in Diastereoselective Reactions
1992
Pure and Appl. Chem. 1992, 64, 1857-1864
14) Acyclic Stereocontrol Via Organogembismetallic Reagents. Part III
1992
Synlett 1992, 633-634
13) Synthese d’Alcoxyallenes Chiraux par Carbocupration d’Acetals Propargyliques. Etude de leur Reactivite à l’Egard d’Organocuprates
1992
Bull. Soc. Chim. Fr. 1992, 129, 171-190
12) Iodocyclisation of Olefinic t-Butyl Ethers: An Easy Stereocontrolled Synthesis of Cis-Substituted Tetrahydrofurans
1992
Tetrahedron Lett. 1992, 33, 1747-1748
1991
11) γ-Tributylstannyl-β-Metallated Acrolein: A Versatile Synthon
1991
Tetrahedron Lett. 1991, 32, 6337-6340
10) Acyclic Stereocontrol through the Metalla-Claisen Rearrangement. Part II
1991
Tetrahedron Lett. 1991, 32, 5973-5976
9) Acyclic Stereocontrol through the Metalla-Claisen Rearrangement. Part I
1991
Tetrahedron Lett. 1991, 32, 5969-5972
8) A Highly Efficient Synthesis of (Z)-γ-Iodo Allylic Alcohols
1991
Tetrahedron Lett. 1991, 32, 5329-5332
7) Diastereoselective Syn or Anti Opening of Propargylic Epoxides. Synthesis of α-Allenic Alcohols
1991
Tetrahedron 1991, 47, 1677-1696
1990
6) Mechanistic Aspects on the Formation of Chiral Allenes from propargylic Ethers and Organocopper Reagents
1990
J. Am. Chem. Soc. 1990, 112, 8042-8047
5) Structure of 1,3,5-Triallyl-4,6-Diphenyl-1,3,5-Triazacyclohexan-2-one
1990
Acta. Cryst. 1990, C46, 1168-1170
1989
4) Copper-Catalyzed Reductive Metallation of a Propargylic Epoxide to an Allenyl Lithium Reagent
1989
Tetrahedron Lett. 1989, 30, 2391-2392
3) Diastereoselective Synthesis of α-Allenic Alcohols from Propargylic Epoxides
1989
Tetrahedron Lett. 1989, 30, 2387-2390
1988
2) Chiral Acetals in Enantio-and Diastereoselective Substitution or Elimination Reactions
1988
Pure & Appl. Chem. 1988, 60, 49-56
1986
1) Are Allenes Formed from Propargylic Ethers Through a Syn or Anti-Displacement?
1986
Tetrahedron Lett. 1986, 27, 5499-5502