Articles
2025
285) Iterative Synthesis of Stereodefined Polyacetals and their Domino-Coates-Claisen Rearrangement
2025
Chem. Sci. 2025, DOI: 10.1039/D4SC08790A
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284) Access to Quaternary-Substituted Cyclobutylsilanes by Ring Opening of Arylbicyclobutanes with Silyllithium Reagents
2025
Angew. Chem. Int. Ed. 2025, e202421235
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2024
283) Stereoselective Synthesis of 1,n-Dicarbonyl Compounds Through Palladium-Catalyzed Ring Opening/Isomerization of Densely Substituted Cyclopropanols
2024
Angew. Chem. Int. Ed. 2024, e202421476
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282) Copper-Catalyzed Carbomagnesiation of 1-Halocyclopropenes
2024
Org. Lett. 2024, 26, 9138-9141
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281) Stereoinvertive SN1 Through Neighboring Group Participation
2024
Angew. Chem. Int. Ed. 2024, e202407602
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280) Synthesis of Stereodefined Polysubstituted Bicyclo[1.1.0]butanes
2024
J. Am. Chem. Soc. (2024), 146, 13748-13753
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279) Stereoselective Nucleophilic Halogenation at CF3-Substituted Non-Classical Carbocation
2024
Org. Lett. 2024, 26, 3657−3660
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2023
278) Highly Diastereoselective Preparation of Tertiary Alkyl Thiocyanates en Route to Thiols by Stereoinvertive Nucleophilic Substitution at Nonclassical Carbocations
2023
Org. Lett. 2023, 25, 8474−8477
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277) Oxenoids as Homologation Partners
2023
Homologation Reactions, Ed. Vittorio Pace, Wiley-VCH Weinheim, 2023, 287-308
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276) Tetrazole Diversification of Amino Acids and Peptides via Silver-Catalyzed Intermolecular Cycloaddition with Aryldiazonium Salts
2023
Angew. Chem. Int. Ed. 2023, 62, e202304740
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275) Selective Terminal Functionalization of Linear Alkanes
2023
Angew. Chem. Int. Ed. 2023, 62, e202306343
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274) Dirhodium(II)-catalyzed enantioselective cyclopropenation of internal alkynes with trifluoromethyl carbene
2023
Chem Catalysis. 2023, 3, 100637
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273) Highly Diastereoselective Preparation of Tertiary Alkyl Isonitriles by Stereoinvertive Nucleophilic Substitution at a Nonclassical Carbocation
2023
Org. Lett. 2023, 25, 2285–2288
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272) Stereospecific Nucleophilic Substitution at Quaternary Carbon Stereocenters
2023
Chem, 2023, 9, 266-279
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271) Stereoselective Construction of Tertiary Homoallyl Alcohols and Ethers by Nucleophilic Substitution at Quaternary Carbon Stereocenter
2023
Angew. Chem. Int. Ed. 2023, 62, e202212425
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2022
270) Stereoselective Preparation of CF3-Containing Cyclopropanes
2022
Org. Lett. 2022, 24, 49, 9076–9080
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269) Synthesis and Functionalization of Tertiary Propargylic Boronic Esters by Alkynyllithium-Mediated 1,2-Metalate Rearrangement of Borylated Cyclopropanes
2022
Org. Lett. 2022, 24, 8901−8906
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268) Directed Diastereoselective Cyclopropanation and Epoxidation of Alkenyl Cyclopropyl Carbinols Derivatives
2022
Org. Lett. 2022, 24, 8322−8325
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267) Regio- and Diastereoselective Carbometalation Reaction of Cyclopropenes
2022
Acc. Chem. Res. 2022, 55, 2848−2868
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266) Stereoselective Synthesis of Polysubstituted Spiropentanes
2022
J. Am. Chem. Soc. 2022, 144, 16732–16736
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265) Borylated Cyclopropanes as Spring-Loaded Entities: Access to Vicinal Tertiary and Quaternary Stereocenters in Acyclic Systems
2022
J. Am. Chem. Soc. 2022, 144, 16298−16302
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264) Preparation of Distant Quaternary Carbon Stereocenters by Double Selective Ring-Opening of 1,1-Biscyclopropyl Methanol Derivatives
2022
Angew. Chem. Int. Ed. 2022, 61, e202203652
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263) Stereoinvertive Nucleophilic Substitution at Quaternary Carbon Stereocenters of Cyclopropyl Ketones and Ethers
2022
Angew. Chem. Int. Ed. 2022, 61, e202203673
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262) Stereospecific Construction of Quaternary Carbon Stereocenters from Quaternary Carbon Stereocenters
2022
J. Am. Chem. Soc. 2022, 144, 7066−7071
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261) Mechanistic Insights on the Selectivity of the Tandem Heck-Ring-Opening of Cyclopropyldiol Derivatives
2022
JACS Au 2022, 2, 3, 687–696
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260) Stereoselective Synthesis Through Remote Functionalization
2022
Nature Synthesis, 2022, 1, 37-48
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2021
259) Stereodivergent Access to Trisubstituted Alkenylboronate Esters through Alkene Isomerization
2021
Org. Lett. 2021, 23, 9194−9198
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258) Directed Regioselective Carbometallation of 1,2-Dialkyl-Substituted Cyclopropenes
2021
Angew. Chem. Int. Ed. 2021, 60, 26368–26372
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257) Alkene Isomerization Revitalizes the Coates-Claisen Rearrangement
2021
Angew. Chem. Int. Ed. 2021, 60, 18509 –18513
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256) Stereoselective Tandem Iridium-Catalyzed Alkene Isomerization-Cope Rearrangement of ω-diene Epoxides: Efficient Access to Acyclic 1,6-Dicarbonyl Compounds
2021
Chem. Sci. 2021, 12, 9328-9332
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255) Stereoselective Sc(OTf)3‐Catalyzed Aldol Reactions of disubstituted Silyl Enol Ethers of Aldehydes with Acetals
2021
Angew. Chem. Int. Ed. 2021, 12765-12769
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254) Regio‐ and Diastereoselective Copper‐Catalyzed Carbomagnesiation for the Synthesis of Penta‐ and Hexa‐Substituted Cyclopropanes
2021
Angew. Chem. Int. Ed. 2021, 60, 11804-11808
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253) Creating Stereocenters within Acyclic Systems by C-C Bond Cleavage of Cyclopropanes
2021
Chem. Rev. 2021, 121, 1, 140-161
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252) Carbon-Carbon Bond Cleavage in Stereoselective Synthesis
2021
Chem. Rev. 2021, 121, 1, 1–2.
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2020
251) Remote Fluorination and Fluoroalkyl(thiol)ation Reactions
2020
Chem. Eur. J. 2020, 26, 15378-15396
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250) Stereospecific Access to Allylboronic Esters Within Acyclic Systems Bearing Distant Tetrasubstituted Stereocenters
2020
Angew. Chem. Int. Ed. 2020, 59, 20434-20438
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249) Stereospecific Nucleophilic Substitution at Tertiary and Quaternary Stereocentres
2020
Chem. Sci. 2020, 11, 9378-9385
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248) Stereoselective Preparation of Distant Stereocenters (1,5) within Acyclic Molecules
2020
ACS Catal. 2020, 10, 7154−7161
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247) Cobalt-Catalyzed Diastereoselective and Enantioselective Hydrosilylation of Achiral Cyclopropenes
2020
Org. Lett. 2020, 22, 4914−4918
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246) Stereoselective Access to Fully Substituted Aldehyde‐Derived Silyl Enol Ethers by Iridium‐Catalyzed Alkene Isomerization
2020
Angew. Chem. Int. Ed. 2020, 59, 15549–15553
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245) The Schulich Faculty of Chemistry, Technion –Israel Institute of Technology I. Marek, Y. Apeloig
2020
Eur. J. Org. Chem. (Editorial), 2020, 3116-3119
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244) Construction of Acyclic Vicinal Tertiary and Quaternary Carbon Stereocenters via a Pd-Catalyzed Allylic Alkylation of Stereodefined Polysubstituted Ketene Aminals
2020
Eur. J. Org. Chem. 2020, 3133-3137
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243) Ru-Catalyzed Isomerization of w-Alkenylboronates towards Stereoselective Synthesis of Vinylboronates with Subsequent in-situ Functionalization
2020
Chem. Sci. 2020, 11, 5944 - 5949
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242) The protective effect of the TSPO ligands 2,4-Di-Cl-MGV-1, CB86, and 1 CB204 against LPS-induced M1 pro-inflammatory activation of microglia
2020
Brain, Behavior, & Immunity - Health 2020, 5, 100083
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241) Alkene Isomerization through Allylmetals as a Strategic Tool in Stereoselective Synthesis
2020
ACS Catal. 2020, 10, 5793−5804
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240) Nucleophilic Substitution at Quaternary Carbon Stereocenters
2020
J. Am. Chem. Soc. 2020, 142, 5543-5548 Corrections: J. Am. Chem. Soc. 2020, 142, 7710-7712
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239) Pd-Catalyzed Enantioselective Hydroalkynylation of Cyclopropenes
2020
ACS Catal. 2020, 10, 1289-1293
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238) Enantioselective Synthesis of Vicinal Tertiary and Quaternary Carbon Stereogenic Centers Within an Acyclic Chain
2020
Angew. Chem. Int. Ed. 2020, 59, 36-49
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2019
237) Catalytic Enantioselective Cyclopropenation of Internal Alkynes: Access to Difluoromethylated Three-Membered Carbocycles
2019
Angew. Chem. Int. Ed. 2019, 58, 18191-18196
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236) Diastereoselective Ring Opening of Fully-Substituted Cyclopropanes via Intramolecular Friedel–Crafts Alkylation
2019
Chem. Sci. 2019, 10, 9548-9554
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235) Regio- and Stereoselective Synthesis of Fully Substituted Silyl Enol Ethers of Ketones and Aldehydes in Acyclic Systems.
2019
Angew. Chem. Int. Ed. 2019, 58, 14995-14999
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234) Regio- and Diastereoselective Copper-Catalyzed Carbometalation of Cyclopropenylsilanes
2019
Org. Lett. 2019, 21, 9162-9165
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233) Highly E-selective, Stereoconvergent Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling of Alkenyl Ethers
2019
Org. Lett. 2019, 21, 2913-2917
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232) A Tandem Iridium-catalyzed ‘Chain-walking’/Cope Rearrangement Sequence
2019
ACS Catal. 2019, 9, 2400-2406
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231) Diastereo- and Enantioselective Preparation of Cyclopropanol and Cyclopropylamine Derivatives
2019
Beilstein J. Org. Chem. 2019, 15, 752-760
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230) Versatility in the Brook Rearrangement for Selective Ring-Opening of Three-Membered Rings Coralie Tugny, Fa-Guang Zhang and Ilan Marek
2019
Chem. Eur. J. 2019, 25, 205-209
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2018
229) Convergent and Flexible Approach to Stereodefined Polyhydroxylated Fragments
2018
Tetrahedron (special issue for Prof. Leon Ghosez), 2018, 74, 6761-6768
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228) Diastereoselective Ring Opening of Alkenylcyclopropanes: Application to the Total Synthesis of C30 Botryococcene and epi-Botryococcene
2018
Angew. Chem. Int. Ed. 2018, 58, 13237-13241.
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227) Efficient and Stereodivergent Synthesis of Unsaturated Acyclic Fragments Bearing Contiguous Stereogenic Elements
2018
Nature Chem. 2018, 10, 1164-1170
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226) Asymmetric Preparation of Polysubstituted Cyclopropanes Based on Direct Functionalization of Achiral Three-Membered Carbocycles
2018
Chem. Rev. 2018, 118, 8415-8434
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225) Diastereo- and Enantioselective Copper Catalyzed Hydroallylation of Disubstituted Cyclopropenes
2018
Chem. Sci. 2018, 9, 6503-6508
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224) Pd-Catalyzed Selective Remote Ring-Opening of Polysubstituted Cyclopropanols
2018
Chem. Eur. J. 2018, 24, 8553-8557
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223) Metal-Catalyzed Remote Functionalization of -Ene Unsaturated Ethers as a New Entry to Functionalized Vinyl Species
2018
Angew. Chem. Int. Ed. 2018, 57, 57, 8012-8016
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222) Asymmetric Rh-Catalyzed Arylation of Cyclopropenes Based on Directed Functionalization of Three-Membered Carbocycles (DFTMC)
2018
Angew. Chem. Int. Ed. 2018, 57, 3682-3686
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221) Walking Metals for Remote Functionalization
2018
ACS Cent. Sci. 2018, 4, 153-165
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220) Rosarium Philosophorum on Organic Synthesis
2018
Isr. J. Chem. 2018, 58, 122-126
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219) Alkene-Zipper Catalyzed Selective and Remote Retro-Ene Reaction of Alkenyl Cyclopropylcarbinols
2018
Adv. Synth. Catal. 2018, 360, 1389-1396
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218) Electrophilic Oxidation of Stereodefined Polysubstituted Silyl Ketene Aminals
2018
Eur. J. Org. Chem. 2018, 614-618
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217) Electrophilic Fluorination of Stereodefined Polysubstituted Silyl Ketene Hemiaminals en route to Tertiary α-Fluorinated Carbonyl Derivatives
2018
Org. Biomol. Chem. 2018, 16, 1079-1082
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216) Asymmetric Catalytic Preparation of Diastereo- and Enantiomerically Enriched Polysubstituted Cyclopropanol and Cyclopropylamine Derivatives
2018
Angew. Chem. Int. Ed. 2018, 57, 1543-1546
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215) Zirconocene-Mediated Selective and Versatile C-C Bond Cleavage of Strained Carbocycles: Scope and Mechanism
2018
J. Org. Chem. 2018, 83, 3497-3515
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2017
214) 2-Cl-MGV-1 Ameliorates Apoptosis in the Thalamus and Hippocampus and Cognitive Deficits after Cortical Infarct in Rats
2017
Stroke 2017, 48, 3366-3364
213) Tandem Hydroalumination/Cu-Catalyzed Asymmetric Vinyl Metalation as a New Access to Enantioenriched Vinylcyclopropane Derivatives.
2017
Org. Lett. 2017, 19, 3970-3973
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212) Enantioselective Construction of Acyclic Quaternary Stereocenters: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Amide Enolates.
2017
J. Am. Chem. Soc. 2017, 139, 9615-9620
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211) Classical and Novel TSPO Ligands for the Mitochondrial TSPO can Modulate Nuclear Gene Expression: Implications for Mitochondrial Retrograde Signaling.
2017
International Journal of Molecular Sciences 2017, 18, 786
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210) Brook Rearrangement as a Trigger for the Formation of Carbene: Formation of Stereodefined Fully-Substituted Cyclobutene Derivatives.
2017
J. Am. Chem. Soc. 2017, 139, 8364-8370
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209) Merging C-H and C-C Bonds Cleavage in Organic Synthesis
2017
Nature Rev. Chem. 2017, 1, 0035
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208) Asymmetric Copper-Catalyzed Carbomagnesiation of Cyclopropenes.
2017
Angew. Chem. Int. Ed. 2017, 56, 6783-6787
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207) Palladium-Catalyzed Oxidative Cyclization of Aniline-Tethered Alkylidenecyclopropanes with O₂; A Facile Protocol to Selectively Synthesize 2- and 3-Vinylindoles.
2017
Chem. Commun. 2017, 53, 216-219
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206) A Unique Pd-Catalyzed Heck Arylation as a Remote Trigger for Cyclopropane Selective Ring-Opening
2017
Nature Comm. 2017, 8, 14200
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205) Enantioselective Allylic Alkylation of Stereodefined Polysubstituted Copper Enolates as an Entry to Acyclic Quaternary Carbon Stereocentre
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Chem. Sci. 2017, 8, 627-630
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204) Diastereoselective Carbometalation of Cyclobutenes
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Chem. Sci. 2017, 8, 334-339
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203) Zirconocene-Assisted Remote Cleavage of C-C and C-O Bonds: Application to Acyclic Stereodefined Metalated Hydrocarbons
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Org. Biomol. Chem., 2016, 14, 10325-10330
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202) Formation of Carbon Quaternary Stereogenic Center in Acyclic Systems via a Sequence of Carbometalation − Intramolecular Cyclization − Silicon Activation
2016
Synthesis 2016, 48, 3279-3286
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201) Oxidation of bis-Sulfinyl Carbanion as the Pivot of Ionic/Radical Tandem Reactions
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Compte Rendu Academie des Sciences 2016, 19, 403-411
200) Preparation and Reactivity of Acyclic Chiral Allylzinc Species via a Zn-Brook Rearrangement
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Angew. Chem. Int. Ed. 2016, 55, 6057-6061
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199) Diastereodivergent Combined Carbometalation − Zinc Homologation – C-C Fragmentation Reaction as an Efficient Tool to Prepare Acyclic Allylic Quaternary Carbon Stereocenters
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Chem. Sci. 2016, 7, 5989-5994
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198) Brook Rearrangement as a Trigger for Ring-Opening strained Carbocycles
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197) Stereoselective Formation of Trisubstituted Ketone Enolates
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Chem. Soc. Rev. 2016, 45, 4552-4566
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194) Merging Allylic C-H Bond Activation and C-C Bond Cleavage en route to the Formation of Quaternary Carbon stereocenter in Acyclic Systems
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193) Asymmetric Copper-Catalyzed Carbozincation of Cyclopropenes en route to the Formation of Diastereo- and Enantiomerically Enriched Polysubstituted Cyclopropanes
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191) The Scientific Bridge: Fifty Years of Germany-Israel Diplomatic Relations
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190) Quinazoline-Based Tricyclic Compounds that Regulate Programmed Cell Death, Induce Neuronal Differentiation, and are Curative in Animal Models for Excitoxicity and Hereditary Brain Disease
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189) Stereodefined Acyclic Trisubstituted Silyl Enol Ethers Towards the Asymmetric Formation of Aldol Products Possessing Quaternary Carbon Stereocenters
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188) Gold(I)-Catalyzed Cycloisomerization of Vinylidenecyclopropane-enes via Carbene or non-Carbene Processes
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187) Forming Stereogenic Centers in Acyclic Systems from Alkynes
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186) Probing the Limits of NMR and VCD Spectroscopies in the Stereochemical Assignment of Chiral ²H₆-Neopentane
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185) Formation of Several Carbon-Carbon Bonds in Acyclic Systems
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184) Cyclopropene Derivatives as a New Entry to Enantioenriched Cyclopropanol and n-Butenal Possessing Quaternary Carbon Stereocenters
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182) Gold and Silver-Catalyzed Intramolecular Cyclizations of Indolylcyclopropenes for the Divergent Synthesis of Azepinoindoles and Spiroindoline Piperidines
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ChemCatChem 2015, 7, 595-600
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181) Selective Carbon-Carbon Bond Cleavage for the Stereoselective Synthesis of Acyclic Systems
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180) Electrophilic Amination: The Case of Nitrenoids
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179) Formation of Three New Bonds and Two Stereocenters in Acyclic Systems by Zinc-Mediated Asymmetric Alkynylation of Acylsilanes, Brook Rearrangement and Ene-Allene Carbocyclization Reactions
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178) Stereodefined Acyclic Trisubstituted Metal Enolates Towards the Asymmetric Formation of Quaternary Carbon Stereocentres
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177) Isoxazole-Embedded Allylic Zinc Reagent for the Diastereoselective Preparation of Highly Functionalized Aldol-Type derivatives Bearing a Stereocontrolled Quaternary Center
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176) Chemistry in Israel−at a Crossroads? (Editorial)
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174) Highly Diastereoselective Preparation of Aldol Products Using New Functionalized Allylic Aluminum Reagents
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172) Advances in Carbolithiation
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Nature 2014 505, 199-203
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169) Modulable and Highly Diastereoselective Carbometalations of Cyclopropenes
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Chem. Eur. J. 2014, 20, 1038-1048
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167) A One-Pot Zinc-promoted Asymmetric Alkynylation/Brook-Type Rearrangement/Ene-Allene Cyclization: Highly Selective Formation of Three New bonds and two Stereocenters in Acyclic Systems
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Angew. Chem. Int. Ed. 2013, 52, 13717-13721
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166) Carboxylate-Assistance for Catalyzed Hydroarylations of Methylenecyclopropanes
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165) Stereodefined Trisubstituted Enolates as a Unique Entry to All-Carbon Quaternary Stereogenic Centres in Acyclic Systems
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Nature Protocols 2013, 4, 749-754
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Acc. Chem. Res. 2013, 46, 1659-1669
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163) Regio- and Stereoselective Carbometallation Reactions of N-Alkynyl-Amides and Sulfonamides
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Beilstein J. Org. Chem. 2013, 9, 526-532.
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162) The Renaissance of Zinc Carbenoid in Stereoselective Synthesis in Acyclic systems
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Organometallics 2013, 32, 942-950
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161) Diastereodivergent Carbometalation/Oxidation/Selective Ring Opening: Formation of All‐Carbon Quaternary Stereogenic Centers in Acyclic Systems†
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Angew. Chem. Int. Ed. 2013, 52, 5333-5337
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160) Carboxylate-assisted Ruthenium(II)-Catalyzed C-H Arylation of 5-Aryl Tetrazoles: Step-Economical Access to Valsartan
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Tetrahedron 2013, 69, 4445-4453
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159) New Advances in Bis(sulfoxides) Chemistry
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Phosphorus Silicon & Related 2013, 188, 367-376
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158) Carboxylate-Assisted Ruthenium(II)-Catalyzed Hydroarylations of Unactivated Alkenes via C–H Cleavage
2013
Angew. Chem. Int. Ed. 2013, 52, 3977-3980
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157) Alkenyl Zinc Reagents in Cross-Coupling Reactions In Cross-Coupling and Heck-Type Reactions 1 − C-C Cross Coupling Using Organometallic Partners
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Science of Synthesis 2012, 765-794
156) Forming All-Carbon Quaternary Stereogenic Centres in Acyclic Systems from Alkynes
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Nature 2012, 490, 522
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155) Convergent Diastereoselective Preparation of Adjacent Quaternary Stereocenters in an Acyclic System
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Org. Biomol. Chem., 2012, 10, 5803-5806 (Special issue for 10th Birthday)
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154) Efficient Brønsted Acid Catalyzed Hydrations and Hydroaminations of (Dicyclopropylmethylene) cyclopropane
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152) Conjugate Additions to Alkylidene Bis-sulfoxides
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Chem. Asian J. 2011, 6, 1825-1833
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Chem. Commun. (Feature article) 2011, 47, 4593-4623
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148) Recent Advances in Carbocupration of α-Heterosubstituted Alkynes
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Beilstein J. Org. Chem. 2010, 6, No. 77. doi:10.3762/bjoc.6.77
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Tetrahedron 2010, 66, 4874-4881
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Eur. J. Org. Chem. 2009, 1749-1756
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134) Enantioselective Construction of all-Carbon Quaternary Stereogenic Carbons in Aldol Reactions
2009
Nature Chemistry, 2009, 1, 128-132
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133) Diastereo- and Enantioselective Zinc Ene-Allene Carbocyclization
2009
Org. Lett. 2009, 11, 1853-1856
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132) Copper-Catalyzed Hydride Transfer Towards the Formation of Alkylidenecyclopropane Derivatives
2009
Chem. Commun. 2009, 292-294
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131) Stereoselective Synthesis of Metalated Cyclobutane Derivatives
2009
Advanced Synthesis and Catalysis 2009, 351, 1005-1008
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2008
130) Zinc Homologation-Elimination Reaction of α-Sulfinyl Carbanions as a New Route to Olefins
2008
Eur. J. Org. Chem. (2008) 4924-4931
129) Zinc Homologation-Elimination Reaction of α-Sulfinyl Carbanions as a New Route to Olefins
2008
Eur. J. Org. Chem. 2008, 4924-4931
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128) Convergent Preparation of Enantiomerically Pure Polyalkylated Cyclopropane Derivatives
2008
Angew. Chem. Int. Ed. 2008, 47, 6865-6868
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127) A Shift in Retrosynthetic Paradigm (Concept article)
2008
Chem. Eur. J. 2008, 14, 7460-7468
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126) Cyclopropenyllithiums as a New Source of 1,1-Bismetalated Cyclopropyl Derivatives
2008
Chem. Commun. 2008, 4300
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125) Synthesis of Sulfoximidoyl-Substituted Triazoles by Huisgen 1,3-Dipolar Cycloaddition
2008
Synlett 2008, 116-118
2007
124) Intramolecular Carbozincation of Unactivated Alkenes Occurs Through a Zinc Radical Transfer Mechanism
2007
J. Am. Chem. Soc. 2007, 129, 15405-15409
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123) Diastereodivergent Synthesis of Enantiomerically Pure Homoallylic Amine Derivatives Containing Quaternary Carbon Stereocenters
2007
Angew. Chem. Int. Ed. 2007, 46, 9291-9294
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122) An Efficient, Facile and General Stereoselective Preparation of Heterosubstituted Alkylidenecyclopropanes
2007
Angew. Chem. Int. Ed. 2007, 46, 8039-8042
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121) Enantiomerically Enriched Cyclopropene Derivatives: Versatile Building Blocks in Asymmetric Synthesis
2007
Angew. Chem. Int. Ed. 2007, 46, 7364-7376; (Corrigenda Angew. Chem. Int. Ed. 2008, 47, 1982)
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120) Creation of Chiral Quaternary Stereocenters in the Carbonyl Allylation Reactions
2007
Chem. Commun. (Feature article), 2007, 43, 1683-1691
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119) Stereodivergent Carbometalation Reactions of Cyclopropenylcarbinols Derivatives
2007
Org. Lett. 2007, 9, 2569-2571
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118) Regio- and Stereoselective Copper-Catalyzed Carbozincation of Alkynylsulfoximines
2007
Org. Lett. 2007, 9, 1259-1261
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2006
117) A Zirconium Promenade; A Efficient Tool in organic Synthesis
2006
Synlett (account), 2006, 501-514
116) Multicomponent Approach for the Creation of Chiral Quaternary Centers in the Carbonyl Allylation Reactions
2006
J. Am. Chem. Soc. 2006, 128, 4642-4649
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115) Chiral Cyclopropenylcarbinols as a New Source of Chiral Alkylidenecyclopropane Derivatives
2006
Angew. Chem. Int. Ed. 2006, 45, 3963-3965
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114) Unsaturated Fatty Alcohol Derivatives as a New Source of Substituted Allylzirconocenes
2006
Angew. Chem. Int. Ed. 2006, 45, 465-468
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2005
113) New Tandem Zn-Promoted Brook Rearrangement/Ene-Allene carbocyclization Reactions
2005
Org. Lett. 2005, 7, 5313-5316
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112) Special issue of Tetrahedron Symposium-in-Print on Multicomponent Reactions
2005
Tetrahedron, 2005, 61, 11309-11519. Guest Editors
111) Stereoselective Functionalization of Cyclopropane Derivatives Using Bromine/Magnesium and Sulfoxide/Magnesium Exchange Reactions
2005
Org. Lett. 2005, 7, 3789-3791
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110) Preparation and Synthetic Transformation of Alkenyl Carbamate into Vinyl Zirconocene Derivatives
2005
Synthesis 2005, 3311-3318
109) Functionalized Organozirconium and Titanium in Organic Synthesis In Functionalized Organometallic Derivatives
2005
Ed. P. Knochel, Wiley-VCH, Weinheim, 2005, 503-540
108) Regiocontrolled Carbometallation Reactions of Ynamides
2005
Synlett 2005, 2098-2100
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107) Synthesis of Chiral Methylenecyclopropanes Derivatives
2005
Synlett 2005, 2239-2241
2004
106) Ambiphilic Zinc Carbenoid as a New Tool for Multicomponent Condensation Reactions
2004
Isr. Chem. Soc. 2004, 16, 22-32
105) Stereoselective Synthesis and Reactivity of Dienyl Zirconocene
2004
Practical Synthetic Procedures Synthesis, 2004, 2411-2417
104) New Regio-, Stereo-, Diastereo-, and Enantioselective One-Pot Reactions Mediated by Organometallic Derivatives
2004
Synthesis 2004, 2411-2417
103) Functionalized Organozirconium and Titanium in Organic Synthesis In Functionalized Organometallic Derivatives
2004
Springer Verlag, 2004, 133-166
102) The Preparation of Organolithium Compounds and Derivatives in The Chemistry of Organolithium Compounds
2004
Eds Rappoport, Z.; Marek, I., John Wiley & Sons, Chichester, 2004, 435-493
101) Carbometallation Reaction in Transition Metals for Fine Chemicals and Organic Synthesis-second edition
2004
Eds C. Bolm, M. Beller, Wiley-VCH, 2004, 563-573
100) Carbometalation Reaction in Metal-Catalyzed Cross-Coupling Reactions- second edition
2004
Eds F. Diederich, A. de Meijere Wiley-VCH, 2004, 395-478
99) Stereoselective Preparation of Deuteriated Dienes by Ring Fragmentation of Metallated Cyclopropylcarbinols
2004
Synlett 2004, 1288-1290
98) Convenient Access to 2-(Trialkylstannyl)cyclopropylamines and Their Application in Palladium-Catalyzed Cross-Coupling Reactions
2004
Eur. J. Org. Chem. 2004, 631-635
97) Diastereoselective Reduction of Cyclopropenylcarbinol: new Access to Anti-Cyclopropylcarbinol Derivatives
2004
Org. Lett. 2004, 6, 341-343
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96) α-Sulfinyl Carbanions as a New Source of Olefins
2004
Org. Lett. 2004, 6, 621-623
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95) From Vinyl Sulfides, Sulfoxides and Sulfones to Vinyl Zirconocene Derivatives
2004
Tetrahedron 2004, 60, 1329-1337
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2003
94) Regio- and Stereoselective Synthesis of Novel E-Alkenyl Carbamate via Carbocupration Reaction
2003
Org. Lett. 2003, 5, 5087-5089
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93) Stereoselective Preparation of Dienyl Zirconocene Complexes via a Tandem Allylic C-H bond Activation-Elimination Sequence
2003
J. Am. Chem. Soc. 2003, 125, 13258-13264
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92) Four-Component Reactions for a New Diastereo- and Enantioselective Synthesis of Chiral Quaternary Centers.
2003
J. Am. Chem. Soc. 2003, 125, 11776-11777
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91) Synthesis and Reactivity of Geminated Organobismetallic Derivatives
2003
Actualite Chimique, special issue on the Present and future in Chemistry, 2003, 17-24
90) Stereoselective Preparation of Functionalized Unsaturated Lactones and Esters via Functionalized Magnesium Compounds
2003
Synthesis 2003, 1797-1802
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89) Reaction of Allylzirconocene Compounds with Isolated or In Situ Generated η⁵ Pentadienyl Fe(CO)₃ /Fe(CO)₂ PPh₃(+1) Cations.
2003
Tetrahedron Lett. 2003, 44, 5909-5912
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2002
88) Sp3 Organozinc Carbenoid Homologation in Organic Synthesis
2002
Tetrahedron Report, 2002, 58, 9463-9475
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87) New Approach to the Stereoselective Synthesis of Metallated Dienes via an Isomerization-Elimination Sequence
2002
J. Am. Chem. Soc. 2002, 124, 10282-10283
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87) New Approach to the Stereoselective Synthesis of Metallated Dienes via an Isomerization-Elimination Sequence
2002
J. Am. Chem. Soc. 2002, 124, 10282-10283
86) New Preparation of Stereodefined α,β-Unsaturated Ketones by Carbomagnesiation of allenyl ketone
2002
Tetrahedron Lett. 2002, 43, 6009-6010
85) New Methods for the Preparation of Sp2 Organometallic derivatives
2002
Synthesis 2002, 2473-2483
84) Carbocupration-Zinc Carbenoids Homologation and β-Elimination Reactions for a New Synthesis of Allenes. Applications to a New Synthesis of Chiral Allenes via Deracemization of Sp3 Organometallic Derivatives
2002
Eur. J. Org. Chem. 2002, 4151-4158
83) Diastereoselective Reduction of Alkenylboronic Esters as a New Method for Controlling the Stereochemistry of up to Three Adjacent Centers and Acyclic Molecules
2002
Org. Lett. 2002, 4, 2861-2863
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82) Functionalized Aminocyclopropanes from Functionalized Organozinc Compounds and N,N Dialkylcarboxamides
2002
Synlett 2002, 879-882
81) Catalytic Asymmetric and Stereoselective Synthesis of Vinyl Cyclopropanes
2002
Synlett 2002, 423-426
80) From Vinyl Sulfides, Sulfoxides and Sulfones to Transition Metal Complexes k
2002
Angew. Chem. Int. Ed. 2002, 41, 1410-1413
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79) Preparation of New Functionalized Cyclopropylmagnesium Reagents
2002
Angew. Chem. Int. Ed. 2002, 41, 351-352
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2001
78) Preface for a special issue of the Journal of Organometallic Chemistry dedicated to Prof. Jean-F. Normant
2001
J. Organomet. Chem. 2001, 624, 1-3
77) Oxidative Addition-β-Elimination: A New Method for the Preparation of Organometallic Compounds
2001
J. Organomet. Chem. 2001, 624, 26-33
76) Diastereoselective Carbozincation of Propargylic Amines
2001
Tetrahedron 2001, 57, 2477-2483
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75) Improved Preparation of Secondary Zinc Iodides by 1,2-Migration of sp3 Carbenoids
2001
Synlett 2001, 818-820
2000
74) Synthesis and Reactivity of sp2 Geminated Organobismetallics
2000
Chem. Rev. 2000, 100, 2887-2900
73) Carbometalation of Unactivated Alkynes via Low Valent Titanium Derivatives
2000
Chem. Commun. 2000, 1849-1850
72) New Allene Synthesis via Carbocupration- Zinc Carbenoid Homologation and β-Elimination
2000
Org. Lett. 2000, 2, 2849-2852
71) Stereoselective Preparation of E-Vinyl Zirconium Derivatives from E or Z-Enol Ether
2000
J. Org. Chem. 2000, 65, 7518-7220
70) First Synthesis and Reactivity of Functionalized Alkynyl Titanium Derivatives.
2000
Synthesis 2000, 917-920
69) Novel Stereoselective and Enantioselective Synthesis of Heterocyclic Compounds by Anionic Method
2000
Actual. Chim. 2000, 3, 60-61
68) Synthesis and Reactivity of Polymetallated Olefins and Functionalized Metallo-Alkynes
2000
Polyhedron 2000, 19, 563-566
66) Fluoroform: An Efficient Precursor for the Trifluoromethylation of Aldehydes
2000
Tetrahedron 2000, 56, 275-283
1999
65) Enantioselective Carbometalation of Unactivated Olefins
1999
J. Chem. Soc. Perkin Trans. 1, 1999, 535-544
64) Iodine Transfer Cyclization Mediated by DIBAL-H/THF
1999
Chem. Commun. 1999, 2375-2376
63) A New Approach Towards the Synthesis of sp3 1,1-Diiodoalkanes
1999
Chem. Commun. 1999, 2207-2208
62) First Synthesis of Metallated Titanacyclopropenes
1999
Synlett 1999, 11, 1939-1941
61) Preparation and Reaction of Functionalized Magnesium Carbenoids
1999
Synlett 1999, 11, 1820-1822
60) The Allyl Zincation of Vinyl Metals. A Computational Study
1999
Org. Lett. 1, 1999, 929-931
59) Enantioselective Carbometalation of Cinnamyl Derivatives: New Access to Chiral Disubstituted Cyclopropanes. Configurational Stability of Benzylic Organozinc Halides
1999
Chem. Eur. J. 1999, 5, 2055
58) Diastereoselective contra-Michael addition of (-)-sparteine/organolithium complexes to secondary chiral cinnamyl amides
1999
Tetrahedron Lett. 1999, 40, 3383-3386
57) Regioselective Addition of n-Butyllithium on Secondary Cinnamyl Amides Michael versus Contra-Michael Process
1999
Tetrahedron Lett. 1999, 40, 3379-3382
56) First Transfer of Chirality in the Fritsch- Buttenberg-Wiechell Rearrangement, via Zinc Carbenoids: A Migration with Retention of Configuration
1999
Tetrahedron Lett. 1999, 40, 1899-1902
1998
55) Preparation and Reaction of 1,n-bimetallic Reagents in Practical Approach in Organozinc Chemistry
1998
Ed. Knochel, P. Oxford University Press, 1998, 119-137
54) Carbometallation Reactions in Metal-Catalyzed Cross-Coupling Reactions
1998
Eds Stang, P.J., Diederich, F. Wiley-VCH, 1998, 271-337
53) Carbometalation Reactions in Transition Metals for Fine Chemicals and Organic Synthesis,
1998
Eds. Bolm, C., Beller, C. Wiley-VCH, 1998, 514-522
52) Diastereoselective Carbometalation of Chiral Vinyl Metals
1998
C. R. Acad. Sci. Paris, t.1, Serie II c 1998, 621-625
51) First Diastereoselective Carbometalation of Chiral Vinyl Metals
1998
Tetrahedron Lett. 1998, 39, 4821-4824
50) Fluoroform: An Efficient Precursor for the Trifluoromethylation of Carbonyl Compounds
1998
Tetrahedron Lett. 1998, 39, 2973-2976
49) Diastereoselective and Enantioselective Intramolecular Amino-Zinc-Enolate Carbometalation Reactions. A New Polysubstituted Pyrrolidines Synthesis
1998
J. Org. Chem. 1998, 63, 2442-2450
48) Amino-Zinc-Enolate Carbocyclization Reactions. New Access to Polysubstituted Piperidines Derivatives
1998
J. Org. Chem. 1998, 64, 566-574
1997
47) Enantioselective Carbolithiation of β-alkylated Styrene
1997
Tetrahedron Lett. 1997, 38, 7523-7526
46) Enantioselective Carbolithiation of Cinnamyl Acetals. New Access to Chiral disubstituted Cyclopropanes
1997
J. Org. Chem. 1997, 62, 4898-4899
45) Zinca-Ene-Allene Cyclizations. A way to Substituted Tetrahydrofurans or Pyrrolidines
1997
Bull. Soc. Chim. Fr. 1997, 134, 333-341
44) Zinca-En-Allene and Zinc-Enolate Cyclization. Towards the Synthesis of Polysubstituted Pyrrolidines
1997
Tetrahedron Lett. 1997, 38, 89-92
43) A Simple and Convenient Method for the Preparation of (Z) or (E)-γ-Iodo Allylics Alcohols and (Z)-β-Iodo Acrolein
1997
Org. Synth. 1997, 74, 194-204
1996
42) Synthesis and Reactivity of sp3 Geminated Organobismetallics
1996
Chem. Rev. 1996, 96, 3241-3267
41) Synthesis of Polysubstituted Stereodefined Olefins via the Reactivity of sp2 -Organogembismetallics
1996
Synthesis 1996, 1499-1508
40) Intramolecular Carbolithiation of Silylated Enynes
1996
Tetrahedron Lett. 1996, 37, 6693-6694
39) Intermolecular Carbolithiation of Silylated Enynes
1996
Tetrahedron Lett. 1996, 37, 6689-6692
38) Diastereoselective Carbometalation of δ-Mono and γ-λ-Disubstituted Z Vinyl Metals
1996
Tetrahedron Lett. 1996, 37, 5873-5876
37) Stereoselective Synthesis of Linear and Angular Triquinanes Skeletons via the Zinca-Ene Allene Reactions
1996
Tetrahedron Lett. 1996, 37, 857-860
36) Diastereoselective Synthesis of Heterosubstituted Organogembismetallic Reagents. Application to a New Propargylmetalation Reaction of Vinyl Metals
1996
Tetrahedron 1996, 52, 7235-7250
1995
35) Stereoselective Synthesis of Polysubstituted Olefins Via the Formation of 1,1-Bimetalloalkenes
1995
Tetrahedron Lett. 1995, 36, 7451-7454
34) Asymmetric Carbolithiation of Cinnamyl Derivatives in the Presence of (-) Sparteine
1995
J. Am. Chem. Soc. 1995, 117, 8853-8854
33) Diastereoselective Reactions of Gembismetallic Derivatives
1995
Synlett 1995, 723-7251
32) Metal-Alkene π-Chelation: A Stereodirecting Effect in Allylzincation Reactions and in Zinc Mediated Cyclopropanations
1995
Tetrahedron Lett. 1995, 36, 3695-3698
31) Stereodefined Substituted Cyclopropyl Zinc Reagents from Gembismetallics
1995
J. Org. Chem. 1995, 60, 2488-2501
30) Zinca-En-Allene Cyclization. Synthesis of Substituted Tetrahydrofurans
1995
Tetrahedron Lett. 1995, 36, 1263-1266
29) Intramolecular Metallo-Ene-Allene Reactions. A New Carbocycles Synthesis
1995
J. Org. Chem. 1995, 60, 863-871
1994
28) Diastereoselective Carbometalation of -Heterosubstituted Vinylmetals
1994
Bull. Soc. Chim. Fr. 1994, 131, 910-918
27) Phenylthioacetylene as a Source of Stereodefined Trisubstituted Alkenes
1994
Tetrahedron Lett. 1994, 35, 6873-6876
26) Carbocyclization of δ-Acetylenic Propargylic Zinc Reagents
1994
Tetrahedron Lett. 1994, 35, 5645-5648
25) Intramolecular Carbometallation of Organozinc Reagents
1994
Tetrahedron 1994, 50, 11665-11692
24) Diastereoselective Carbometalation of Vinyl Metals
1994
J. Org. Chem. 1994, 59, 4154-6166
23) Carbolithiation of Cinnamyldialkylamines. Stereochemistry of the Li to Zn transmetalation and Configurational Stability of Benzylic Organozinc Halides
1994
J. Org. Chem. 1994, 59, 2925-2926
1993
22) Cyclic Steocontrol Via Organobismetallic Reagents. Part VI. Stereodefined Substituted Cyclopropyl Zinc Reagents
1993
Tetrahedron Lett. 1993, 34, 7575-7578
21) Intramolecular Carbometallation of Secondary Organozinc Reagents
1993
Tetrahedron Lett. 1993, 34, 6053-6056
20) Selective Monoalkylation of Organogembismetallics Via an Intramolecular Nucleophilic Substitution
1993
Synlett 1993, 665-666
18) Carbocyclisation of Functionnalized Zinc Organometallics
1993
Synlett 1993, 266-268
17) Cyclic Stereocontrol Via Organobismetallic Reagents. Part V. Diastereoselective Synthesis of Substituted Cyclopropyl Zinc Reagents by the Metalla-Claisen Reaction
1993
Tetrahedron Lett. 1993, 34, 2303-2306
1992
16) Resolution and Asymmetric Synthesis of Ortho-Substituted (Benzaldehyde) Tricarbonylchromium Complexes
1992
J. Am. Chem. Soc. 1992, 114, 8288-8290
15) Organobismetallic Zinc Reagents: Their Preparation and Use in Diastereoselective Reactions
1992
Pure and Appl. Chem. 1992, 64, 1857-1864
14) Acyclic Stereocontrol Via Organogembismetallic Reagents. Part III
1992
Synlett 1992, 633-634
13) Synthese d’Alcoxyallenes Chiraux par Carbocupration d’Acetals Propargyliques. Etude de leur Reactivite à l’Egard d’Organocuprates
1992
Bull. Soc. Chim. Fr. 1992, 129, 171-190
12) Iodocyclisation of Olefinic t-Butyl Ethers: An Easy Stereocontrolled Synthesis of Cis-Substituted Tetrahydrofurans
1992
Tetrahedron Lett. 1992, 33, 1747-1748
1991
11) γ-Tributylstannyl-β-Metallated Acrolein: A Versatile Synthon
1991
Tetrahedron Lett. 1991, 32, 6337-6340
10) Acyclic Stereocontrol through the Metalla-Claisen Rearrangement. Part II
1991
Tetrahedron Lett. 1991, 32, 5973-5976
9) Acyclic Stereocontrol through the Metalla-Claisen Rearrangement. Part I
1991
Tetrahedron Lett. 1991, 32, 5969-5972
8) A Highly Efficient Synthesis of (Z)-γ-Iodo Allylic Alcohols
1991
Tetrahedron Lett. 1991, 32, 5329-5332
7) Diastereoselective Syn or Anti Opening of Propargylic Epoxides. Synthesis of α-Allenic Alcohols
1991
Tetrahedron 1991, 47, 1677-1696
1990
6) Mechanistic Aspects on the Formation of Chiral Allenes from propargylic Ethers and Organocopper Reagents
1990
J. Am. Chem. Soc. 1990, 112, 8042-8047
5) Structure of 1,3,5-Triallyl-4,6-Diphenyl-1,3,5-Triazacyclohexan-2-one
1990
Acta. Cryst. 1990, C46, 1168-1170
1989
4) Copper-Catalyzed Reductive Metallation of a Propargylic Epoxide to an Allenyl Lithium Reagent
1989
Tetrahedron Lett. 1989, 30, 2391-2392
3) Diastereoselective Synthesis of α-Allenic Alcohols from Propargylic Epoxides
1989
Tetrahedron Lett. 1989, 30, 2387-2390
1988
2) Chiral Acetals in Enantio-and Diastereoselective Substitution or Elimination Reactions
1988
Pure & Appl. Chem. 1988, 60, 49-56
1986
1) Are Allenes Formed from Propargylic Ethers Through a Syn or Anti-Displacement?
1986
Tetrahedron Lett. 1986, 27, 5499-5502